Electrosynthesis of trimethylorthoformate on BDD electrodes
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The Cl2 evolution reaction was studied at highly boron-doped diamond thin film electrodes. The comparison of this carbonaceous material with graphite and glassy carbon points out the similar behavior in terms of diagnostic parameters and related mechanisms ...
Synthetic B-doped diamond thin film electrodes were tested for electroanal. detection of 2-naphthol. This redox reaction was studied by cyclic voltammetry in aq. acidic soln. Well-resolved oxidn. waves were obsd. and the voltammetric peaks exhibited naphth ...
The electrochem. behavior of some model org. compds. on boron-doped synthetic diamond thin film electrodes, obtained by HF-CVD on p-Si substrate was investigated. Only reactions involving simple electron transfer like hydroquinone/benzoquinone are active i ...
The morphol. examn. and the structural anal. of DSA-O2 electrodes [IrO2-Ta2O5 (70:30 mol%) coating] show that at moderate firing temp. (about 550 Deg), sepn. of phases occurs with the formation of agglomerates of IrO2 crystals and amorphous Ta2O5. At highe ...
DSA type electrodes (IrOx/Ti) were prepd. by induction heating technique which allows a rapid decompn. of the precursor under anaerobic conditions. With this type of electrode, an activation process is obsd. in cyclic voltammetry which can be related to th ...
The objectives of this study were to validate new experimental techniques used to measure the log P of protonated drugs, and to investigate the inter- and intramolecular forces influencing the partitioning behavior of β-blockers in isotropic biphasic solve ...
The service life of SnO2-Sb2O5 coated anodes prepd. by the spray pyrolysis technique using Ti or Ti/IrO2 substrate, was studied under galvanostatic conditions (100 mA cm-2 in 1M H2SO4 at 25 Deg). The presence of an IrO2 interlayer between the Ti substrate ...