Publication
Nuclear magnetic resonance study of xenon-131 interacting with surfaces: Effective Liouvillian and spectral analysis
Related publications (132)
129Xe Dynamic Nuclear Polarization Demystified: The Influence of the Glassing Matrix on the Radical Properties
Rolf Gruetter, Andrea Capozzi, Jean-Noël Hyacinthe, Thanh Phong Kevin Lê, Emma Linnea Wiström
129Xe dissolution dynamic nuclear polarization (DNP) is a controversial topic. The gold standard technique for hyperpolarized xenon magnetic resonance imaging (MRI) is spin exchange optical pumping, which received FDA approval in 2022. Nevertheless, the ve ...
2024Quantification of Native Lignin Structural Features with Gel-Phase 2D-HSQC0 Reveals Lignin Structural Changes During Extraction
Jeremy Luterbacher, Stefania Bertella
Our ability to study and valorize the lignin fraction of biomass is hampered by the fundamental and still unmet challenge of precisely quantifying native lignin's structural features. Here, we developed a rapid elevated-temperature H-1-C-13 Heteronuclear S ...
Wiley-V C H Verlag Gmbh2024Deuterated TEKPol Biradicals and the Spin-Diffusion Barrier in MAS DNP
David Lyndon Emsley, Federico De Biasi, Yu Rao, Dominik Józef Kubicki, Amrit Venkatesh
The sensitivity of NMR spectroscopy is considerably enhanced by dynamic nuclear polarization (DNP). In DNP polarization is transferred from unpaired electrons of a polarizing agent to nearby proton spins. In solids, this transfer is followed by the transpo ...
2023Towards optical MAS magnetic resonance using optical traps
Giovanni Boero, Nergiz Sahin Solmaz, Reza Farsi, Jens Anders
Higher magic angle spinning (MAS) frequencies than currently available are desirable to improve spectral resolution in NMR and EPR systems. While conventional strategies employ pneumatic spinning limited by fluid dynamics, this paper demonstrates the devel ...
Amsterdam2023Influence of DNP Polarizing Agents on Biochemical Processes: TEMPOL in Transient Ischemic Stroke
Mor-Miri Mishkovsky, Jean-Noël Hyacinthe, Mario Gaetano Lepore, Thanh Phong Kevin Lê, Lara Buscemi Estefanell
Hyperpolarization of 13C by dissolution dynamic nuclear polarization (dDNP) boosts the sensitivity of magnetic resonance spectroscopy (MRS), making possible the monitoring in vivo and in real time of the biochemical reactions of exogenously infused 13C-lab ...
2023Diamond-Based Nanoscale Quantum Relaxometry for Sensing Free Radical Production in Cells
Mayeul Sylvain Chipaux, Hoda Shirzad
Diamond magnetometry makes use of fluorescent defects in diamonds to convert magnetic resonance signals into fluorescence. Because optical photons can be detected much more sensitively, this technique currently holds several sensitivity world records for r ...
WILEY-V C H VERLAG GMBH2022Mechanistic studies of DNP and applications of hyperpolarized probes to study renal physiology and metabolism
Dissolution dynamic nuclear polarization (dDNP) is a powerful technique that enhances the magnetic resonance signal of nuclear spins by several orders of magnitude. DNP relies on the principle of cross-relaxation by electron spins driven out of equilibrium ...
EPFL2021Bulk Hyperpolarization of Inorganic Materials
David Lyndon Emsley, Snaedis Björgvinsdóttir
Solid-state NMR spectroscopy is a well-established method to obtain atomic-level information about the structure of inorganic materials, but its use is often limited by low sensitivity. We review how solvent generated dynamic nuclear polarization can be us ...
SWISS CHEMICAL SOC2021Pure Isotropic Proton Solid State NMR
David Lyndon Emsley, Daria Torodii, Pinelopi Moutzouri, Bruno Simões de Almeida
Resolution in proton solid state magic angle sample spinning (MAS) NMR is limited by the intrinsically imperfect nature of coherent averaging induced by either MAS or multiple pulse sequence methods. Here, we suggest that instead of optimizing and perfecti ...
AMER CHEMICAL SOC2021Sensitivity Enhancements in Lithium Titanates by Incipient Wetness Impregnation DNP NMR
David Lyndon Emsley, Michael Allan Hope, Pierrick Berruyer, Pinelopi Moutzouri, Snaedis Björgvinsdóttir
Solid-state NMR spectroscopy is a widely used method for investigating structural and electronic properties of inorganic materials, but its use is often limited by low sensitivity. Here, we show how solvent-generated dynamic nuclear polarization can be use ...
AMER CHEMICAL SOC2020