Preparation of fluorocyclopropanes by reductive dechlorination of chlorofluorocyclopropanes
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2,2-Diethoxyvinyllithium (I) can be readily generated from 2-bromo-1,1-diethoxyethylene by treatment with butyllithium. Reaction of I with electrophiles e.g. chlorotrimethylsilane gives Me3SiCH:C(OEt)2. When dissolved in THF, I can be stored at -25 DegC fo ...
1-Bromo-3,5-bis(trifluoromethyl)benzene was selectively prepd. by treatment of 1,3-bis(fluoromethyl)benzene with N,N'-dibromo-5,5-dimethylhydantoin in strongly acidic media. A no. of synthetically useful reactions via 3,5-bis(trifluoromethyl)phenylmagnesiu ...
(Z)-(3,3-dimethylbicyclo[2.2.1]hept-2-ylidene)methyllithium can be readily generated by treatment of (Z)-3-bromomethylene-2,2-dimethylbicyclo[2.2.1]heptane with Me3CLi. At -75 Deg, the organometallic intermediate is configurationally stable and reacts with ...
5-amino-6-methyl-2-benzimidazolone (AMBI), used in the manufacture of dyes, was characterised as a biorecalcitrant compound by means of different biodegradability tests. In order to enhance the biodegradability of this important pollutant, the application ...
This study focuses on the mineralization of 5-amino-6-methyl-2-benzimidazolone (AMBI), an important precursor in the industrial production of dyes, through an integrated Fe(III) photoassisted–biological system without addition of other electron acceptor th ...
The TELEMAC project brings new methodologies from the Information and Science Technologies field to the world of water treatment. TELEMAC offers an advanced remote management system which adapts to most of the anaerobic wastewater treatment plants that do ...
The electrochem. oxidn. of phenol in the presence of NaCl for wastewater treatment was studied at Ti/SnO2 and Ti/IrO2 anodes. The presence of NaCl catalyzes the anodic oxidn. of phenol only at Ti/IrO2 anodes due to the participation of electrogenerated ClO ...
N-[2-(hydroxymethyl)phenyl]pyrrole was found to be amenable to selective a-metalation. Trapping with a variety of electrophilic reagents afforded the expected products with moderate to high yields. Derivs. formed by treatment of the organometallic intermed ...
In this paper, probabilistic observers are considered for a class of continuous biological processes described by mass-balance-based models. It is assumed that the probability density functions (PDFs) of the uncertain parameters and inputs of the model, as ...
A new strategy based upon the intramol. SNAr reaction was developed for the synthesis of I, the 14-membered F-O-G macrocyclic ring system of teicoplanin. Thus, treatment of acyclic precursor II (X = F) with CsF or K2CO3/18-crown-6 in DMF at room temp. for ...