Publication

SCOOPY-Reaktionen : Die Regioselektivität der Alkenol-Synthese

1972
Journal paper

Abstract

Ph3P+CH2R (R = H, Me) reacted with aldehydes R1CHO (R1 = n-C5H11, Me2PrC, Ph) in the presence of BuLi and HCHO to give primary alkenols R1CH:CRCH2OH; ketones R2R3CO [R2, R3 = Me, Ph or (CH2)4, (CH2)5] and spatially crowded aldehydes gave secondary and tertiary alcs. R2R3C(OH)CR:CH2. A b-oxido phosphonium ylide was a reaction intermediate. [on SciFinder (R)]

Official source

https://infoscience.epfl.ch/record/81472?ln=en

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chatbot

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

SCOOPY-Reaktionen : Die Regioselektivität der Alkenol-Synthese

Graph Chatbot

Chat with Graph Search

Exploiting the Dual Reactivity of o-Isocyanobenzamide: Three-Component Synthesis of 4-Imino-4H-3,1-benzoxazines

Synthesis of Polysubstituted 4,5,6,7-Tetrahydrofuro[2,3-c]pyridines by a Novel Multicomponent Reaction

Exploiting the Dual Reactivity of o-Isocyanobenzamide: Three-Component Synthesis of 4-Imino-4H-3,1-benzoxazines

Synthesis of Polysubstituted 4,5,6,7-Tetrahydrofuro[2,3-c]pyridines by a Novel Multicomponent Reaction