A review with 37 refs. about C-C linkages with organometallic compds., esp. the Cu-catalyzed alkylation of Grignard reagents, giving satd. and unsatd. hydrocarbons optionally substituted by functional groups, and regio- and stereoselective olefin synthesis with allylpotassium compds. [on SciFinder (R)]
Mark Pauly, Francis Julian Panetta, Seiichi Eduardo Suzuki Erazo, Quentin Christian Becker, Yingying Ren, Davide Pellis
Alkynes are found in a multitude of natural or synthetic bioactive compounds. In addition to the capacity of these chemical motifs to impact the physicochemical properties of a molecule of interest, the well-established reactivity of alkynes makes them ...
Simon Nessim Henein, Charles Baur, Loïc Benoît Tissot-Daguette, Hubert Pierre-Marie Benoît Schneegans, Quentin Gubler