Optional Site Selectivity in the Metalation of o- and p-Anisidine through Matching of Reagents with Neighboring Groups
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The hydrogen storage properties of a new family of isostructural metal organic frameworks are reported. The frameworks M-2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn; dobpdc(4-) = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are analogous to the widely studied M-2(do ...
The chemical transformation of carbon dioxide into useful products becomes increasingly important as CO2 levels in the atmosphere continue to rise as a consequence of human activities. In this article we describe the direct hydrogenation of CO2 into formic ...
The Materials Genome is in action: the molecular codes for millions of materials have been sequenced, predictive models have been developed, and now the challenge of hydrogen storage is targeted. Renewably generated hydrogen is an attractive transportation ...
Complex hydrides such as LiBH4 and LiNH2 exceed the gravimetric hydrogen density of transition metal hydrides by one order of magnitude. However, hydrogen in complex hydrides is covalently bound and arranged in subunits e.g. [NH2]- and [BH4] - with a fixed ...
The goal of this rapport is to present an overview of the different hydrogen storage technologies, currently available for industrial application or at earlier stages of development. In order to identify the water and mechanical work requirements for compr ...
We reported herein a facile and scalable preparation process for MoS2-decorated ZnxCd1-xS hybrid photocatalysts for hydrogen generation. ZnxCd1-xS nanopowder was first prepared from commercially available precursors employing a solution based process. MoS2 ...
In water, spin–lattice relaxation times (T1) and calibration curves for chemical shifts have been determined for the 13C and the 1H (C) atoms in HCOOH, HCOONa, CO2, Na2CO3 and NaHCO3 by NMR spectroscopy. These data facilitate kinetic and mechanistic studie ...
Y(BH4)3 is one of the candidates for solid-state hydrogen storage, which contains 9.06 wt% of hydrogen. In this study, the thermal properties of Y(BH4)3 synthesized via two different methods are extensively examined. One method relies on the solid-solid me ...
Materials exhibiting reversible hydrogen adsorption with high gravimetric and volumetric capacities are sought for use in on-board storage systems of hydrogen fuel cell-powered vehicles. Microporous metal-org. frameworks with high internal surface areas ha ...
