Assembly and reactivity of nanoparticles at liquid / liquid interfaces
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This work deals with the modelling of electrochemical reactors with bipolar electrodes. We give a numerical model which enables us to compute electrical current and potential distributions in an electrochemical cell of any type of geometry in two and three ...
The electrochem. oxidn. of benzoic acid (BA) was studied on boron-doped diamond electrodes on acid medium by cyclic voltammetry and bulk electrolysis. In the potential region where the supporting electrolyte is stable, reactions occur, resulting in the los ...
Fundamental expressions for analyzing potential modulated fluorescence (PMF) responses were derived within the framework of a phenomenological model for adsorption and transfer of ionic species across polarized liquid|liquid interfaces. For small periodic ...
The ab initio mol. dynamics method is extended to treat exchange of electrons between mols. and a reservoir at fixed chem. potential. The method is based on a rigorously grand-canonical d. functional approach using sep. potential energy surfaces for each o ...
Excitons and trions in a CdTe modulation-doped quantum well are investigated by picosecond three-pulse four-wave mixing experiments as a function of temperature in the low-density regime. We show that trions are mobile for high enough temperatures. The dif ...
The dynamics of photoresponses associated with heterogeneous quenching of zinc tetrakis(carboxphenyl)porphyrin (ZnTPPC) and ferrocene derivatives at the water/1,2-dichloroethane interface were studied by intensity modulated photocurrent spectroscopy (IMPS) ...
A novel electrochemiluminescence (ECL) detector is presented in this article. The detector is applied for micellar electrokinetic chromatographic separation of dichlorotris(2,2′-bipyridyl)ruthenium(II) hydrate [Ru(bpy)] and dichlorotris(1,10-phenanthroline ...
A device, method and kit for the electrophoretic separation and purification of charged and neutral compounds in an analyte solution. The device comprises a chamber (1), at least one wall of which is composed of a chemical buffering system (4). A potential ...
Electrochem. promotion of dispersed RuO2 catalyst on yttria-stabilized zirconia (YSZ) monolith was studied in a monolithic catalytic reactor fabricated from YSZ solid electrolyte. This new design showed an important increase in ethylene conversion to CO2 b ...
The term values of the ground and excited Rydberg states of alkali metal atoms trapped in rare gas matrixes were derived from an empirical model potential. The anal. potential smoothly connects the Coulomb potential near the core with the shielded Coulomb ...