Characterization of segregation in a tubular polymerization reactor by a new chemical method
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The PhD thesis deals with the optimization of the reaction calorimetry technique to monitor chemical reactions in supercritical fluids. The aim is to develop this thermal analysis technique to monitor the heat released by a chemical reaction in a high pres ...
Catalytic gas-phase abatement of air containing 250 ppm of isopropanol (IPA) was carried out with a novel dielectric barrier discharge (DBD) reactor with the inner catalytic electrode made of sintered metal fibers (SMF). The optimization of the reactor per ...
Two types of stainless steel microstructured reactors for catalytic gas-phase reactions have been developed and characterized with respect to their thermal behaviour under non-stationary temperature conditions. One of the reactors used (FTC-I) allowed peri ...
A comprehensive program of integral experiments, largely based on the measurement of reaction rate distributions, was carried out recently in the PROTEUS zero-power research reactor at the Paul Scherrer Institute in Switzerland, employing a fuel lattice re ...
The method and app. for carrying out electrochem. promoted catalytic reactions, i.e., catalytic reactions where the catalytic rate and selectivity is modified by applying an elec. current or potential between the porous catalyst film which is deposited on ...
A high pressure reactor calorimeter was developed to study chem. reactions in supercrit. fluids. Non-dimensional anal. of the heat transfer mechanism in the calorimeter verifies the application of the Nusselt correlation in scCO2. The reactor's cover and f ...
The aim of this work is to develop a microstructured reactor based on filamentous catalysts for the Oxidative Steam-Reforming of Methanol (OSRM), to produce hydrogen as feed for a fuel cell, in an autothermal way. Hydrogen is produced by the methanol Steam ...
A novel dismantlable monolithic-type electrochem. promoted catalytic reactor and "smart" sensor-catalytic reactor unit has been constructed and tested for hydrocarbon oxidn. and NO redn. by C2H4 in presence of O2. In this novel reactor, thin (.apprx.20-4 ...
Recent explosions at two chemical plants, one in the United States and one in Japan, involving hydroxylamine manufacture underline the lack of mechanistic understanding about this industrially relevant compound. The basic chemical properties of hydroxylami ...
During the early stages of research and development chemical industry needs flexible and versatile tools to investigate chemical reaction systems. An important part of the optimisation of a process considering economic factors, risk analysis and environmen ...