Publications related to Supported glass fibers catalysts for novel multi-phase reactor design

Molybdenum Based Electrocatalysts for Hydrogen Evolution in Water

The limited fossil fuel resources and the increasing levels of greenhouse gases in the atmosphere are the driving forces in the research of alternative ways of energy production and storage. The use of solar energy is expected to grow as our society claims ...

EPFL2013

The development of gold catalysts for use in hydrogenation reactions

Fernando Cardenas Lizana

With increasing emphasis placed on cleaner chemical synthesis, energy efficiency and waste minimisation, the manufacture of pharmaceuticals and fine chemicals is undergoing a progressive shift from conventional stoichiometric organic processes to a harness ...

Springer2013

Copper Catalyzed N-Arylation of Amidines with Aryl Boronic Acids and One-Pot Synthesis of Benzimidazoles by a Chan–Lam–Evans N-Arylation and C–H Activation/C–N Bond Forming Process

Jieping Zhu

Mono-N-arylation of benzamidines 1 with aryl boronic acids 2 was effectively achieved in the presence of a catalytic amount of Cu(OAc)2 and NaOPiv under mild aerobic conditions. Combining this step with an intramolecular direct CH bond functionalization, c ...

Amer Chemical Soc2012

Kinetics and Mechanism of Formic Acid Decomposition in Aqueous Solution using Ruthenium Pre-catalysts with Hydrophilic Phosphine Ligands

Weijia Gan

Hydrogen holds the potential to be an alternative to replace fossil fuels in the future. The tremendous research effort dedicated to the issue of hydrogen storage has led to considerable advancements in the development of both adsorption materials and chem ...

EPFL2012

Enhanced rate of arene hydrogenation with imidazolium functionalized bipyridine stabilized rhodium nanoparticle catalysts

Paul Joseph Dyson, Rosario Scopelliti, Ning Yan, Ryan Dykeman

The imidazolium functionalized bipyridine compounds, {4,4'-bis-[7-(2,3-dimethylimidazolium)heptyl]-2,2'-bipyridine}(2+) (BIHB) and {4,4'-bis[(1,2-dimethylimidazolium)methyl]-2,2'-bipyridine}(2+) (BIMB), were prepared and used as Rh nanoparticle ...

2011

Recent Advances in the Liquid-Phase Synthesis of Metal Nanostructures with Controlled Shape and Size for Catalysis

Lioubov Kiwi

Recent advances in the liquid-phase synthesis of metal nanostructures of different sizes and shapes are reviewed regarding their catalytic properties. The controlled synthesis of nanostructures is based on the colloid chemistry techniques in the solution, ...

2009

Novel catalytic applications of carbon nanofibers on sintered metal fibers filters as structured supports

Marina Ruta

Supported metal catalysts are important from both an industrial and a scientific point of view. They are used, amongst others, in large-scale processes such as catalytic reforming, hydrotreating, polymerization reactions and hydrogenations. Often, these ca ...

EPFL2008

Biphasic Hydrogenation over PVP Stabilized Rh Nanoparticles in Hydroxyl Functionalized Ionic Liquids

Paul Joseph Dyson, Lioubov Kiwi, Gabor Laurenczy, Zhaofu Fei, Ning Yan, Rocio Micaela Crespo Quesada, Yuehui Li, Xuemei Yang

Polyvinylpyrrolidone stabilized rhodium nanoparticles are highly sol. in hydroxyl-functionalized ionic liqs., providing an effective and highly stable catalytic system. In hydrogenation reactions, excellent results were obtained, and transmission electron ...

2008

Homogeneous catalytic decomposition of formic acid for high pressure hydrogen generation

Céline Fellay

The main obstacles in the widespread use of hydrogen as energetic alternative to fossil fuels are storage problems intrinsically linked to its extremely light and explosive nature. Since no ideal storage systems currently exist, reversible fixation of hydr ...

EPFL2008

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Albert Renken, Lioubov Kiwi, Martin Grasemann

Systematic studies of mass transfer interactions with intrinsic reaction kinetics were performed for the threephase selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) over a modified Pd/CaC

{O}_{3}

catalyst under solvent ...

2008

Supported glass fibers catalysts for novel multi-phase reactor design

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Molybdenum Based Electrocatalysts for Hydrogen Evolution in Water

The development of gold catalysts for use in hydrogenation reactions

Copper Catalyzed N-Arylation of Amidines with Aryl Boronic Acids and One-Pot Synthesis of Benzimidazoles by a Chan–Lam–Evans N-Arylation and C–H Activation/C–N Bond Forming Process

Kinetics and Mechanism of Formic Acid Decomposition in Aqueous Solution using Ruthenium Pre-catalysts with Hydrophilic Phosphine Ligands

Enhanced rate of arene hydrogenation with imidazolium functionalized bipyridine stabilized rhodium nanoparticle catalysts

Recent Advances in the Liquid-Phase Synthesis of Metal Nanostructures with Controlled Shape and Size for Catalysis

Novel catalytic applications of carbon nanofibers on sintered metal fibers filters as structured supports

Biphasic Hydrogenation over PVP Stabilized Rh Nanoparticles in Hydroxyl Functionalized Ionic Liquids

Homogeneous catalytic decomposition of formic acid for high pressure hydrogen generation

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

The development of gold catalysts for use in hydrogenation reactions

Novel catalytic applications of carbon nanofibers on sintered metal fibers filters as structured supports

Kinetics and Mechanism of Formic Acid Decomposition in Aqueous Solution using Ruthenium Pre-catalysts with Hydrophilic Phosphine Ligands

Biphasic Hydrogenation over PVP Stabilized Rh Nanoparticles in Hydroxyl Functionalized Ionic Liquids

Homogeneous catalytic decomposition of formic acid for high pressure hydrogen generation

Molybdenum Based Electrocatalysts for Hydrogen Evolution in Water

Enhanced rate of arene hydrogenation with imidazolium functionalized bipyridine stabilized rhodium nanoparticle catalysts

Recent Advances in the Liquid-Phase Synthesis of Metal Nanostructures with Controlled Shape and Size for Catalysis

Copper Catalyzed N-Arylation of Amidines with Aryl Boronic Acids and One-Pot Synthesis of Benzimidazoles by a Chan–Lam–Evans N-Arylation and C–H Activation/C–N Bond Forming Process

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring