Hydrogen production by catalytic cracking of methane over nickel gauze under periodic reactor operation
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Exptl. investigations of the thermal bulk polymn. of styrene (I) in pilot plants of different sizes were done. Each pilot plant consisted of a tubular recycle reactor connected in series with a tubular reactor, both completely filled with Sulzer motionless ...
Nonsteady-state kinetics was used for the detn. of the reaction mechanism of a heterogeneous catalytic reaction, and the characteristic shape of the time evolution curves of the concns. at the outlet of the reactor was assocd. with rate-limiting steps. Add ...
Particle tagging in a tokamak provides an attractive method for studying transport mechanisms. The injection of test particles at the plasma edge and the subsequent measurement of the evolution of their concentration at the centre can be used to quantify t ...
The experimentally observed rise in the single pass methanol production with CO2 and H-2 (T = 200 degreesC, P = 4.3 bar) by in situ product removal over a perm-selective Nafion (R) membrane is verified by model simulations. For this purpose, software was d ...
Catalytic hydrogenation of NO2- in water to N2 over Pd-supported on different woven fibrous materials was studied. Low porosity C fiber, low porosity D-type glass fiber, and composite (glass covered by g-Al2O3) fiber were used. Pd dispersion was compared f ...
The advantage of coupling a diffuse-reflectance infrared cell with a continuous-feed recycle reactor for in situ kinetic and mechanistic studies is illustrated in the study of CO2 methanation over Ru/TiO2. From transient and steady-state experiments, metal ...
A reactor concept designed as a bubble column staged with fibrous catalytic layers is tested on pilot-scale for the redn. of nitrite to N by H. CO2 is used to neutralize the hydroxide ions produced during hydrogenation of nitrite. The effective reaction ra ...
Periodic operation was applied to CO2 hydrogenation to CH4 at 383 K on 2% Ru/TiO2. A continuous feed recycle reactor combined with a diffuse reflectance IR cell and a mass spectrometer was used to follow simultaneously the gas phase CO2 and CH4 as well as ...
Diffuse Reflectance IR Fourier-Transform (DRIFT) spectroscopy is an increasingly popular technique in catalysis research as it permits in situ observation of the reactor bed in powd. or granular form. However, DRIFTS in its conventional form suffers from t ...
HCHO is prepd. in high yield and selectivity by the dehydrogenation of MeOH in the presence of catalysts contg. metallic Na or >=1 Na compd. at 300-800 Deg. Na2CO3 was heated under H at 5 Deg/min and the temp. maintained during this heating process at 100 ...