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Several basic models presented in the literature for reactions with a stop-effect yield virtually the same results under steady state conditions. Such a situation takes place for dehydration of alcohols and the deamination of primary amines. It has been proved that a simple transient behaviour after a stop in the supply of the reactant will not make it possible to distinguish between the models. However, a considerable difference in the mean reaction mte under forced concentration oscillations between the models can be observed. The difference decreases with an increase in the cycling time.
Paul Joseph Dyson, Martin Hulla, Dmitry Vasilyev