NIR Lanthanide Luminescence by Energy Transfer from Appended Terpyridine-Boradiazaindacene Dyes
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The diastereoselective synthesis of chiral coordination compounds with d metals proved the effectiveness of the pinene-bipyridine approach in predetermining the chirality at the metal centre. The strong Lewis acidic character of lanthanide cations required ...
The first part of this short review focuses on the insertion of luminescent lanthanide ions into molecular compounds. The main requirements for the development of highly luminescent chelates with potential applications in biomedical analysis and time-resol ...
A DTPA-based chelate containing one phosphinate group was conjugated to a generation 5 polyamidoamine (PAMAM) dendrimer via a benzylthiourea linkage. The Gd(III) complex of this novel conjugate has potential as a contrast agent for magnetic resonance imagi ...
Two unsymmetrical ditopic hexadentate ligands designed for the simultaneous recognition of two different trivalent lanthanide ions have been synthesized, LAB2 and LAB3, where A represents a tridentate benzimidazole-pyridinebenzimidazole coordination unit, ...
Based on the ligand LAB the new heterobitopic ligands LAB2, LAB3, LAB4 and LAB5 have been designed and synthesised. The five ligands were designed to selectively form heterobimetallic complexes of composition LnLn'(L)36 when reacted with a pair of ...
Basic thermodynamic considerations are used to rationalize the formation of thermotropic mesophases incorporating aromatic ligands for trivalent lanthanide metal ions (Ln). Standard flat and bent molecular interfaces, separating the central binding unit fr ...
The hexadentate bispidine-based ligand 2,4-bis(2-pyridyl)-3,7-bis(2-methylenepyridine)-3,7-diazabicyclo[3.3.1]nonane-9-on-1,5-bis(carbonic acid methyl ester), L-6m, with four pyridine and two tertiary amine donors, based on a very rigid diazaadamantane-der ...
Experimental uncertainties concerning the coordination mode of trivalent plutonium in concentrated LiCl have led us to theoretically evaluate the f-f transitions of a series of rare earth aquo and chloro complexes. The calculation of Pr(III), U(III), Np(II ...
Four tetracatenar (L1–L4) and one hexacatenar (L5) ligands, derived from the diaza-18-crown-6 framework, are synthesized and characterized. In these ligands, the amine functions are fitted with benzoyloxybenzyl linker groups, attached either with a carbony ...
The incommensurate palmierite-like structure of beta-K5Yb(MoO4)(4), potassium ytterbium tetramolydate, has been refined in the (3 + 1)- dimensional monoclinic superspace group X2/m(0 rho 0) 00, with X = [0 0 0 0; 1/2 1/2 0 0; 0 0 1/2 1/2; 1/2 1/2 1/2 1/2] ...