Brillouin-scattering observation of the TA-TO coupling in SrTiO3
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Four galactofuranose-containing disaccharides have been prepared utilising various thioimidates [Galf-SC(NR)XR′] and suitably protected acceptors as key precursors. We observed that the efficiency of the coupling reactions was particularly dependent on the ...
To gain insight into the biol. properties of tetramic acid lactam cylindramide 1, the analogs 4a-d bearing a cyclopentane ring instead of the pentalene unit were prepd. by tandem conjugate addn./enolate trapping of cyclopentenone 10; a Sonogashira or Still ...
The dynamics of excitons and trions in CdTe modulation-doped quantum wells are studied as a function of temperature by three-pulse four-wave mixing experiments. It is shown that trions are localized by interface roughness scattering and/or by the remote io ...
A series of relatively low-cost ionic liquids, based on the N-butyronitrile pyridinium cation C(3)CNpy, designed to improve catalyst retention, have been prepared and evaluated in Suzuki and Stille coupling reactions. Depending on the nature of the an ...
The invention concerns the introduction of a coupling group to 6-O-Alkylguanine DNA alkyltransferase from a 6-O-Alkylguanine-coupling group deriv. that enables the immobilization of the enzyme for subsequent anal. The coupling group is bound covalently to ...
Brillouin scattering showing an unusual low temperature softening of some transverse modes in SrTiO3 had been reported previously. The earlier data, complemented by newer Brillouin results, and supplemented by high quality hyper Raman data on the soft mode ...
Toluene oxidn. over Pb/Li/MgO is investigated in a tubular fixed bed reactor at low conversions. A periodic process alternating toluene oxidn. in absence of oxygen in the feed and regeneration of the catalyst by oxygen presents important changes in product ...
1-Alkenyl chlorides, bromides or iodides, e.g., cis-1-chloro-1-octene, can be obtained with very high cis selectivities by Wittig reactions with a-chloro, a-bromo and a-iodo ylides derived from (2-MeOCH2C6H4)3P. The corresponding a-methoxy substituted ylid ...
The exciton-polariton states of quantum wells embedded in planar semiconductor microcavities are usually described by assuming in-plane wave vector conservation. In this work we consider the two main k(parallel to)-scattering mechanisms, namely the polarit ...
A theor. model is presented to account for the Fano-like interference lineshapes on multiphonon continua in the electronic spectrum of NO in rare-gas solids. The model is based on the coupling of the optical transitions to 1 single local mode, while the la ...