Electrochemical promotion of Pt catalysts for gas phase reactions
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Platinum coatings on Ti were prepd. by a two-step process: partial thermal decompn. of chloroplatinic acid followed by electroredn. of the coating. Effects of prepn. temp. and of cathodic polarization on the roughness factor were studied. Roughness factors ...
The electrochemical promotion of heterogeneous catalytic reactions is a new development which draws the attention of the scientific community as much to fundamental research as to the possible direct applications of this phenomenon in automotive and in ind ...
IrO2 and boron-doped diamond electrodes were tested by preparative electrolysis of simple model compds. in acid medium. In oxidn. reactions of more complex mechanism than simple electron transfer, these electrodes are active only at potentials of simultane ...
The catalytic activity of IrO2 catalyst used as an electrode on a YSZ solid electrolyte cell for the gas phase combustion of ethylene can be increased by electrochem. pre-treatment. Thus, the polarization of the IrO2 electrode for 90 min at 300 mA, relativ ...
In order to investigate the origin of the effect of non faradaic electrochem. modification of catalytic activity (NEMCA), a Kelvin probe was used to measure in situ the changes induced in the work function of an IrO2 catalyst film deposited on yttria-stabi ...
Among the numerous base metals tested for DSA type electrodes (e.g., titanium and its alloys, zirconium, niobium etc.), tantalum is a potentially excellent substrate owing to its good elec. cond. and corrosion resistance, and the favorable dielec. properti ...
The electrochem. behavior of some model org. compds. on boron-doped synthetic diamond thin film electrodes, obtained by HF-CVD on p-Si substrate was investigated. Only reactions involving simple electron transfer like hydroquinone/benzoquinone are active i ...
The performance of the electrolytic ozone generation using a solid polymer electrolyte (SPE) and Pb anode is described. This anode has been prepd. by application of Pb powder on a porous Ti substrate coated with IrO2 layer (Ti/IrO2/Pb anode). Electrochem. ...
The influence of the polarization of the RuO2/YSZ interface on the electrochem. promotion of RuO2 catalysts was studied by temp. programmed desorption and high temp. cyclic voltammetry measurements. The desorption activation energy of adsorbed oxygen decre ...
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution has been investigated using different oxide electrodes. A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective oxidn. occurs ...