A Metallacage Encapsulating Chloride as a Probe for a Solvation Scale in Ionic Liquids
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A review, with over 209 refs., is given on the prepn. and structures of all known salts of the known homopolyat. cations of the chalcogens and halogens. The structures of these cations, many of which are nonclassical and cluster-like, arise from pos. charg ...
Simplified vibrational densities of states for five different carbonates are constructed using measured IR and Raman spectra. From the spectroscopic models we calculate thermodynamic and thermoelastic properties of magnesite, calcite, aragonite, dolomite, ...
Reactions of X2 (X = Br, I), P4 and Ag(CH2Cl2)[Al(OR)4] [R = C(CF3)3] in suitable ratios to prep. naked polyphosphorus cations were carried out and led to products which suggested these elusive cations as intermediates. At temps. >-30 Deg to rt the initial ...
Previous measurements of SixHm- anions and electrons in the afterglow of silane discharges are analyzed here. A model of plasma anion chemistry includes two sources of anions, two possible causes of x-->x+1 anion growth, and anion loss by mutual neutraliza ...
New mercury organic compounds with 1-3 metal centers and different substituents were synthesized as anion-selective ionophores. They were incorporated into solvent polymeric membranes, and the selectivity, slope of response, response time, emf repeatabilit ...
Retention of cesium in yttria stabilized zirconia (YSZ) was studied experimentally and discussed on the basis of its solubility estimated on a thermodynamic basis. The retention was investigated experimentally by determination of the temperature dependence ...
To answer the intriguing question whether or not endothermic microbial growth exists, and in particular, to verify Heijnen and van Dijken's prediction (1992), acetotrophic methanogen, Methanosarcina barkeri, has been cultivated in a highly sensitive bench- ...
A review with 48 refs. The topics discussed include mass and energy balances for open and non-steady state systems, calcn. of reaction enthalpies, and enthalpy balance in aerobic and anaerobic growth. [on SciFinder (R)] ...
Specific volumes of forsterite and San Carlos olivine have been measured by in-situ X-ray diffraction at simultaneously high pressure and high temperature up to 7 GPa and 1300 K in a cubic-anvil press coupled to synchrotron radiation. No difference could b ...
A computationally efficient and rigorous thermodynamic model (ISORROPIA) that predicts the physical state and composition of inorganic atmospheric aerosol is presented. The advantages of this particular model render it suitable for incorporation into urban ...