A Versatile Synthetic Path to Thiol Containing Polysiloxanes

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The Effect of Thiol Structure on Allyl Sulfide Photodegradable Hydrogels and their Application as a Degradable Scaffold for Organoid Passaging

Intestinal organoids are useful in vitro models for basic and translational studies aimed at understanding and treating disease. However, their routine culture relies on animal-derived matrices that limit translation to clinical applications. In fact, ther ...

Wiley-V C H Verlag Gmbh2020

Synthesis of DNA‐encoded disulfide‐ and thioether‐cyclized peptides

Christian Heinis, Van Manh Pham, Milan Bergeron-Brlek

DNA-encoded chemical library technologies enable the screening of large combinatorial libraries of chemically and structurally diverse molecules, including short cyclic peptides. A challenge in the combinatorial synthesis of cyclic peptides is the final st ...

2020

En route to CO2-containing renewable materials: catalytic synthesis of polycarbonates and non-isocyanate polyhydroxyurethanes derived from cyclic carbonates

Paul Joseph Dyson, Felix Daniel Bobbink, Antoine Philippe Van Muyden

Combining CO2-chemistry with biomass conversion allows renewable polymeric materials including polycarbonates and polyhydroxyurethanes (PHUs) to be generated. The demand for robust materials with modular properties that can be prepared on an industrial sca ...

Royal Society of Chemistry2019

Electrical energy generated by silicone elastomers filled with nanospring- carbon- nanotubes

Frank Nüesch

Dielectric elastomer generators (DEGs) are flexible capacitors that convert mechanical into electrical energy. They rely on an external voltage source to charge the capacitor during each operation cycle. An alternative to this is an autonomous DEG which op ...

Royal Society of Chemistry2019

3D Printing and Supercritical Foaming of Hierarchical Cellular Materials

Matteo Gregorio Modesto Marascio

Hierarchical porous structures have been gathering interest in different fields owing to their unique properties associated with their multi-scale features. The observation of natural materials brought new insights into the functionality of cellular materi ...

EPFL2018

Development of functionalized alginate-based hydrogels to reduce fibrosis in the transplantation of microencapsulated cells

François Rémi Pierre Noverraz

Nowadays, the development of cell therapy relies mainly on the advances made toward cell microencapsulation which allows to evade the need for immunosuppression during cell transplantation. Among the materials considered for cell encapsulation, hydrogels d ...

EPFL2018

High Permittivity Silicones for Dielectric Elastomer Actuators

Simon Johannes Dünki

Many technical advances of modern society sprout from the creation of specially customized polymer materials exhibiting unique combinations of properties uncharted so far. Amid this plurality of highly versatile materials, the class of electroactive polyme ...

EPFL2017

Self-Healing Fiber-Reinforced Composites with Tailored Supramolecular Matrices

Federica Sordo

Fiber Reinforced Composites (FRCs), due to their intrinsic heterogeneity, are generally affected by complex multi-scale failure mechanisms leading to the formation of matrix cracks that are difficult to detect and repair. FRCs with the ability to heal and ...

EPFL2016

Mechanochemically Responsive Surfaces and Soft Tissue Adhesive Interfaces Generated via Controlled Radical Polymerization

Nariye Cavusoglu Ataman

Thin coatings applied to surfaces dramatically improve the properties of materials. Thus, they have found application in a broad variety of areas including biomedicine, nanotechnology, bioelectronics and optics, amongst others. Polymer brushes prepared via ...

EPFL2016

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