Molecular vibrationA molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 1013 Hz to approximately 1014 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm−1 and wavelengths of approximately 30 to 3 μm. For a diatomic molecule A−B, the vibrational frequency in s−1 is given by , where k is the force constant in dyne/cm or erg/cm2 and μ is the reduced mass given by .
Toroidal momentIn electromagnetism, a toroidal moment is an independent term in the multipole expansion of electromagnetic fields besides magnetic and electric multipoles. In the electrostatic multipole expansion, all charge and current distributions can be expanded into a complete set of electric and magnetic multipole coefficients. However, additional terms arise in an electrodynamic multipole expansion. The coefficients of these terms are given by the toroidal multipole moments as well as time derivatives of the electric and magnetic multipole moments.
