Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets

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Computational Studies for the Design of Metalloenzyme Mimics

Guido Frisari

At present, there is no general standard automated method for engineering metalloenzymes, industrially-relevant systems able to catalyze environmentally friendly reactions. One of the most studied natural metalloenzymes is the second isoform of human carbo ...

EPFL2023

Using Complex Hydrides for Hydrogen Storage and Direct Borohydride Fuel Cells for Electricity Production

Youngdon Ko

Hydrogen storage and utilization are the technologies to achieve carbon-neutral energy systems with renewable energy sources. Among the various materials that have been investigated, complex hydrides are a material exhibiting high gravimetric hydrogen dens ...

EPFL2023

Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions

Nukorn Plainpan, Jantira Chimlert

Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Va ...

WILEY-V C H VERLAG GMBH2023

Where is the money ? A decomposition of monetary flows behind fossil fuels

François Maréchal, Jonas Schnidrig, Xiang Li, Raphaël Briguet

Transition from fossils to renewables is leading to radical societal changes. Shifting the capital from fossils to renewables is commonly accompanied with political concerns, such as energy autonomy, domestic employment etc. Despite a decreasing trend in r ...

DTU Construct2022

A Benders decomposition for maximum simulated likelihood estimation of advanced discrete choice models

Michel Bierlaire, Claudia Bongiovanni

In this paper, we formulate a mixed integer linear program (MILP) for the simulated maximum likelihood estimation (MLSE) problem and devise a Benders decomposition approach to speed up the solution process. This framework can be applied to any advanced dis ...

2022

Stability and Reactivity of a Polyoxymethylene Dimethyl Ether over Typical Catalysts for Diesel Emission Control

Oliver Kröcher, Davide Ferri

Polyoxymethylene dimethyl ethers (OME) produced from methanol are considered as potential substitutes of Diesel fuel. Emissions of formaldehyde and other components have been observed, particularly under cold-start conditions in engine test-bench experimen ...

SPRINGER/PLENUM PUBLISHERS2023

Decomposition Strategy for Districts as Renewable Energy Hubs

François Maréchal, Cédric Terrier, Luise Middelhauve

In light of the energy transition, it becomes a widespread solution to decentralize and to decarbonize energy systems. However, limited transformer capacities are a hurdle for large-scale integration of solar energy in the electricity grid. The aim of this ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Logic Synthesis From Incomplete Specifications Using Disjoint Support Decomposition

Giovanni De Micheli, Andrea Costamagna

Approximate logic synthesis is an emerging field that tolerates errors in the synthesized logic circuits for better optimization quality. Indeed, in many computing problems, the requirement of preserving the exact functionality either results in unnecessar ...

IEEE2022

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

Development of C-C and C-O bond cleavage catalysts for the depolymerization of plastics

Wei-Tse Lee

Chemical recycling of plastics provides more flexibility for materials circulation than landfill disposal or incineration. Intensive research efforts have been devoted to maximizing the efficiency of chemical recycling through catalyst development. The fro ...

EPFL2022

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