Publication

Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper-iron oxide|TiO2-cobaloxime photocathode

Related publications (32)

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Rosario Scopelliti, Euro Solari, Albert Ruggi, Vincent Artero, Fiorella Lucarini

Cobalt(II) complexes featuring hexadentate amino-pyridyl ligands have been recently discovered as highly active catalysts for the Hydrogen Evolution Reaction (HER), whose high performance arises from the possibility of assisting proton transfer processes v ...

ROYAL SOC CHEMISTRY2023

Molecular engineering of low-cost, efficient, and stable photosensitizers for dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Lukas Pfeifer, Marina Freitag, Jing Gao, Zhongjin Shen

The cost, stability, and photovoltaic performance of photosensi-tizers play a key role in the commercialization of dye-sensitized solar cells (DSCs). Herein, three novel sensitizers termed ZS10, ZS11, and ZS12 are described based on the simple chemical str ...

Cell Press2023

Bulk Heterojunction Organic Semiconductor Photoanodes: Tuning Energy Levels to Optimize Electron Injection

Kevin Sivula, Jun Ho Yum, Liang Yao, Nestor Guijarro Carratala, Yongpeng Liu, Arvindh Sekar, Han-Hee Cho, Barbara Alexandra Primera Darwich, Juan Manuel Moreno Naranjo

The use of a bulk heterojunction of organic semiconductors to drive photoelectrochemical water splitting is an emerging trend; however, the optimum energy levels of the donor and acceptor have not been established for photoanode operation with respect to e ...

AMER CHEMICAL SOC2022

Solar Water Splitting Using Earth-Abundant Electrocatalysts Driven by High-Efficiency Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Hong Zhang, Dan Ren

Hydrogen is considered as the "holy grail" for the energy community. One of the most promising strategies to produce hydrogen is to split water using renewable energy such as solar radiation. The abundance of water and solar energy enables the potential of ...

WILEY-V C H VERLAG GMBH2022

Modeling and assessment of high-temperature photo-electrochemical devices

Ronald Ramiro Gutierrez Perez

In this thesis, the feasibility and performance of photo-driven electrochemical (PEC) devices working at elevated temperatures (T>700 K) is investigated and modeled. In such high-temperature PEC devices, a part of the solar spectrum is used for generating ...

EPFL2022

Engineering of PEM-PEC photocathodes for solar-driven hydrogen production

Marina Caroline Michèle Caretti

Earth has always been in perpetual evolution, but today we must face its rapid change due to human activity. The intensification of industrial activities and transportation to support our modern lifestyles are the main causes of climate change and the adve ...

EPFL2022

Water photo-oxidation on self-assembled organic/Co3O4 metal junctions in biphasic systems

Hubert Girault, Astrid Johana Olaya Avendano, Julieta Soledad Riva

A microwater vertical bar butyronitrile (W vertical bar BCN) interface was used to study the effect of the interfacial chemical polarization on the efficiency of the visible-light induced water oxidation reaction (WOR) by the electron acceptor/ photosensit ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Photo‐Electrochemical Conversion of CO 2 Under Concentrated Sunlight Enables Combination of High Reaction Rate and Efficiency

Sophia Haussener, Etienne Boutin, Mahendra Patel, Silvan Suter

Photo-electrochemical production of solar fuels from carbon dioxide, water, and sunlight is an appealing approach. Nevertheless, it remains challenging to scale despite encouraging demonstrations at low power input. Higher current densities require notable ...

Wiley2022

Suppressed recombination for monolithic inorganic perovskite/silicon tandem solar cells with an approximate efficiency of 23%

Michael Graetzel, Peng Wang, Yang Li, Xiaoyu Zhang, Shilong Wang

Potentially temperature-resistant inorganic perovskite/silicon tandem solar cells (TSCs) are promising devices for boosting efficiency past the single-junction silicon limit. However, undesirable non-radiative recombination generally leads to a significant ...

Keai Publishing Ltd2022

Modeling the Photostability of Solar Water-Splitting Devices and Stabilization Strategies

Sophia Haussener, Fredy Intelligent Nandjou Dongmeza

The practical implementation of photoelectrochemical devices for hydrogen generation is limited by their short lifetimes. Understanding the factors affecting the stability of the heterogeneous photoelectrodes is required to formulate degradation mitigation ...

2022