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The synthesis of the alkoxide [OC(tBu)(CF3)2]− by the reaction of tBuM-reagents (M = Li; MgX) with hexafluoroacetone was attempted. This alkoxide was anticipated to be a good building block for novel weakly coordinating anions. However, in all attempted sy ...
The synthesis of five half sandwich ruthenium(II) trichlorogermyl complexes of the type [(η6-Arene)Ru(PR3)Cl(GeCl3)] (PR3 = Phosphane and phosphite ligands; Arene = p-cymene or C6H5-OC2H4OH) is reported: [(η6-p-cymene)Ru(P(OMe)3)Cl(GeCl3)] (1), [(η6-p-cyme ...
Substantial signal enhancements achieved by using parahydrogen in catalytic hydrogenations are powerful tools for mechanistic studies of chemical reactions involving molecular H-2. Potentially, this technique can be extended to other reaction classes, prov ...
A high mol. wt. water sol. acrylamide based polymer having improved flocculating and dewatering properties is provided. The polymer is prepd. by a process in which a small quantity of a chain branching agent is added to the polymn. reaction mixt. continuou ...
(Ecole Polytechnique Federale De Lausanne (Epfl), Switz.).2002
A high mol. wt. water sol. acrylamide based polymer having improved flocculating properties is provided. The polymer is prepd. by a process, in which a small quantity of a chain branching agent such as methylenebisacrylamide is added to the polymn. reactio ...
A process for prepg. a water sol. polymer comprises: providing a polymn. reaction mixt. comprising one or more polymerizable ethylenically unsatd. monomers; polymg. the ethylenically unsatd. monomers; and adding to the reaction mixt. during polymn. one or ...
(Ecole Polytechnique Federale De Lausanne (EPFL), Switz.).2002