Concept
Chimie supramoléculaire
Publications associées (385)
Disentangling constraints using viability evolution principles in integrative modeling of macromolecular assemblies
Dario Floreano, Matteo Dal Peraro, Matteo Thomas Degiacomi, Andrea Maesani, Giorgio Elikem Tamo, Sylvain Träger
Predicting the structure of large molecular assemblies remains a challenging task in structural biology when using integrative modeling approaches. One of the main issues stems from the treatment of heterogeneous experimental data used to predict the archi ...
Nature Publishing Group2017Engineering the self-assembly of diketopyrrolopyrrole-based molecular semiconductors via an aliphatic linker strategy
Kevin Sivula, Nestor Guijarro Carratala, Xavier Adrian Jeanbourquin, Xiaoyun Yu, Andrea Gasperini, Emilie Aude Marie Ripaud
The solid-state self-assembly of molecular semiconductors is a key aspect for controlling the optoelectronic properties of organic electronic materials. Herein, we investigate the use of a flexible linker strategy to control the self-assembly of a solution ...
2017PdII2L4-type coordination cages up to three nanometers in size
Rosario Scopelliti, Kay Severin, Suzanne Maria Jansze, Matthew David Wise
The utilization of large ligands in coordination-based self-assembly represents an attractive strategy for the construction of supramolecular assemblies more than two nanometers in size. However, the implementation of this strategy is hampered by the fact ...
2017Synthesis and Characterisation of Semiaromatic Polyamides Comprising Benzofurobenzofuran Repeating Units
Rosario Scopelliti, Farzaneh Fadaei Tirani, Holger Frauenrath, Daniel Görl, Alberto Fabrizio, Bilal Özen, Thomas Schmaltz, Julien Philippe Cretenoud
Semiaromatic polyamides are attractive engineering polymers owing to their outstanding thermo-mechanical properties. To expand the scope of semiaromatic polyamides by additional optoelectronic features, one may consider the incorporation of extended pi-con ...
2017Mode Evolution in Strongly Coupled Plasmonic Dolmens Fabricated by Templated Assembly
Jürgen Brugger, Olivier Martin, Duncan Thomas Lindsay Alexander, Massimo Mastrangeli, Jérémy Butet, Valentin Flauraud, Gabriel David Bernasconi
Plasmonic antennas have enabled a wealth of applications that exploit tailored near-fields and radiative properties, further endowed by the bespoke interactions of multiple resonant building blocks. Specifically, when the interparticle distances are reduce ...
2017Engineering of supramolecular self-assembly in solution-processed organic semiconductors
Organic semiconductors have recently emerged as a promising alternative to standard inorganic semiconductors for many commercial applications. Their ability to be processed from solution combined with their unique mechanical resistance paves the way for lo ...
EPFL2017Synthesis of Responsive Two-Dimensional Polymers via Self-Assembled DNA Networks
Duncan Thomas Lindsay Alexander, Ulrich Aschauer, Hao Yu
Despite a growing interest in two-dimensional polymers, their rational synthesis remains a challenge. The solution-phase synthesis of a two-dimensional polymer is reported. ADNA-based monomer self-assembles into a supra-molecular network, which is further ...
Wiley-V C H Verlag Gmbh2017Adhesion and interfacial healing between supramolecular hybrid networks and glass substrates
Véronique Michaud, Federica Sordo
Adhesion towards glass and interfacial healing of partially supramolecular hybrid polymer networks featuring a range of H-bdnds content were investigated through two dedicated adhesion test methods. In a first series of tests, adhesion strength was measure ...
Elsevier2017Molecular Strategies for Morphology Control in Semiconducting Polymers for Optoelectronics
Solution-processable semiconducting polymers have been explored over the last decades for their potential applications in inexpensively fabricated transistors, diodes and photovoltaic cells. However, a remaining challenge in the field is to control the sol ...
Schweizerische Chemische Gesellschaft2017Structural characterization of framework-gas interactions in the metal-organic framework Co-2(dobdc) by in situ single-crystal X-ray diffraction
Wendy Lee Queen, Miguel Gonzalez
The crystallographic characterization of framework-guest interactions in metal-organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with ...
2017