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Concept
Lever rule
Résumé
In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
In an alloy or a mixture with two phases, α and β, which themselves contain two elements, A and B, the lever rule states that the mass fraction of the α phase is
where
is the mass fraction of element B in the α phase
is the mass fraction of element B in the β phase
is the mass fraction of element B in the entire alloy or mixture
all at some fixed temperature or pressure.
Suppose an alloy at an equilibrium temperature T consists of mass fraction of element B. Suppose also that at temperature T the alloy consists of two phases, α and β, for which the α consists of , and β consists of . Let the mass of the α phase in the alloy be so that the mass of the β phase is , where is the total mass of the alloy.
By definition, then, the mass of element B in the α phase is , while the mass of element B in the β phase is . Together these two quantities sum to the total mass of element B in the alloy, which is given by . Therefore,
By rearranging, one finds that
This final fraction is the mass fraction of the α phase in the alloy.
Before any calculations can be made, a tie line is drawn on the phase diagram to determine the mass fraction of each element; on the phase diagram to the right it is line segment LS. This tie line is drawn horizontally at the composition's temperature from one phase to another (here the liquid to the solid). The mass fraction of element B at the liquidus is given by wBl (represented as wl in this diagram) and the mass fraction of element B at the solidus is given by wBs (represented as ws in this diagram). The mass fraction of solid and liquid can then be calculated using the following lever rule equations:
where wB is the mass fraction of element B for the given composition (represented as wo in this diagram).
Source officielle
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