Concept
Hydroformylation
Publications associées (132)
Ketenimines from Isocyanides and Allyl Carbonates: Palladium-Catalyzed Synthesis of β,γ-Unsaturated Amides and Tetrazoles
Qian Wang, Jieping Zhu, Mathias Mamboury, Guanyinsheng Qiu
The reaction of allyl ethyl carbonates with isocyanides in the presence of a catalytic amount of Pd(OAc)2 provided ketenimines through b-hydride elimination of the allyl imidoylpalladium intermediates. The insertion of the isocyanide into the p-allyl Pd co ...
Wiley-Blackwell2016Pd-Nanoparticles Confined Within Hollow Polymeric Framework as Effective Catalysts for the Synthesis of Fine Chemicals
Encapsulation of metal nanoclusters in porous solid polymer materials is a promising approach to combine the outstanding properties of both, heterogeneous and homogeneous catalysts. We report heterogeneous nano-engineered catalysts containing Pd-nanopartic ...
Springer/Plenum Publishers2016Hydrocarbon oxidation reactivity in iron metal-organic frameworks
High-valent iron-oxo intermediates are implicated in a variety of oxidative enzymes, many of which are capable of the selective partial oxidn. of strong aliph. and arom. C-H bonds. However, mol. iron-oxo species often lack stability, decaying via pathways ...
American Chemical Society2015Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands
Paul Joseph Dyson, Gabor Laurenczy, Katerina Stefania Sordakis
The chemical transformation of CO2 and bicarbonates into useful products becomes increasingly impor- tant as the atmospheric CO2 level has reached 400 ppm. Here a small library of sulfonated aryl mono- phosphines and aryl diphosphines was tested as stabili ...
Elsevier2015