Publications associées à Acide téréphtalique

Kinetic Network Modeling of the Catalytic Upgrading of Biomass's Acetate Fraction to Aromatics

Jeremy Luterbacher, Jher Hau Yeap, Bartosz Rozmyslowicz, Ahmed Mohamed Ibrahim Elkhaiary

The acetate fraction is the fourth most abundant fraction by weight in many plant species and can be easily extracted as acetic acid in high yields. We have previously shown that acetic acid obtained from steam pretreated beech wood could be upgraded in a ...

Amer Chemical Soc2023

Separable Brønsted acidic imidazolium salts for polysaccharide hydrolysis in water

Kedar Ashok Abhyankar

The current reliance on limited petrochemical resources and the resulting ecological outcomes have made the exploration of alternative chemical and energy feedstocks invaluable. As such, the development of sustainable processes with a less harmful total en ...

EPFL2023

Degradation of plastic materials into terephthalic acid (tpa), ethylene glycol and/or other monomers that form the plastic materials

Berend Smit, Kyriakos Stylianou, Christopher Patrick Ireland, Samantha Lynn Anderson

The invention relates to a method for degradation of plastic materials into terephthalic acid (TPA)and/or ethylene glycol and/or other monomers that form the plastic materials. ...

2020

Generation of hydroxyl radical during chlorination of hydroxyphenols and natural organic matter extracts

Urs von Gunten, Eva Maria Rodriguez Franco

The generation of hydroxyl radicals ((OH)-O-center dot) during the chlorination of air saturated solutions of different hydroxyphenols (hydroquinone, resorcinol, catechol, gallic and tannic acids) at pH 7 has been determined by the formation of phenol (in ...

2020

Post-synthesis deposition of mesoporous niobic acid with improved thermal stability by kinetically controlled sol–gel overcoating

Jeremy Luterbacher, Florent Emmanuel Héroguel, Yuan-Peng Du

Niobia is a well-known solid acid catalyst owing to its intrinsic Brønsted and Lewis acidity. However, catalyst development with this oxide has been limited by our ability to control its pore structure and thermal stability. Here we report a novel post-syn ...

Royal Society of Chemistry2019

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum

Claudius Morchutt

This thesis comprises the study of two types of 2D materials, those stabilized by non-covalent and those by covalent interactions. They are synthesized and studied on well-defined metallic surfaces in ultra-high vacuum (UHV). The self-assembly of terephtha ...

EPFL2016

Antioxidant Assay Based on Quenching of Photocatalytically Generated Reactive Oxygen Species

Hubert Girault, Mohamad Hojeij, Qifeng Zhang

A method based on photogeneration of OH radicals in water from TiO2 nanoparticles was developed to study the kinetics of oxidation of organic molecules which were used as biological antioxidants. The kinetics of oxidation of terephthalic acid as a referenc ...

Elsevier Science Inc2016

A Pyridine-Based Ligand with Two Hydrazine Functions for Lanthanide Chelation: Remarkable Kinetic Inertness for a Linear, Bishydrated Complex

Lothar Helm, Eva Jakab Toth

To study the influence of hydrazine functions in the ligand skeleton, we designed the heptadentate HYD ligand (2,2',2 '',2 ''-(2,2'-(pyridine-2,6-diyl)bis(2-methylhydrazine-2,1,1-triyl)) tetraacetic acid) and compared the thermodynamic, kinetic, and relaxa ...

American Chemical Society2015

Aqueous Fabrication of pH-Gated, Polymer-Brush-Modified Alumina Hybrid Membranes

Harm-Anton Klok, Caroline Sugnaux

In this Article, we studied the surface immobilization of five organic-acid-modified atom-transfer radical polymerization (ATRP) initiators based on salicylic acid, catechol, phthalic acid, and m- and p-benzoic add on alumina, and we also investigated the ...

Amer Chemical Soc2013

RF-plasma pretreatment of surfaces leading to TiO2 coatings with improved optical absorption and OH-radical production

César Pulgarin, Juan Kiwi, Sami Rtimi, Christophe Roussel, Oualid Baghriche

Evidence is presented for the RF pretreatment of polyester enhances the TiO2 coating generation of oxidative species/radicals under a low level actinic light irradiation. After 30 min RF-plasma pretreatment of the polyester samples, the fastest bacterial i ...

Elsevier2013