Concept

Eau lourde

Publications associées (114)

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Pd-catalyzed intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by reduction of C(sp3)-Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3-disubstituted oxindoles in high yields and enantioselectiviti ...

Wiley-Blackwell2017

DEMO port plug design and integration studies

Minh Quang Tran

The EUROfusion Consortium established in 2014 and composed by European Fusion Laboratories, and in particular the Power Plant Physics and Technology department aims to develop a conceptual design for the Fusion DEMOnstration Power Plant, DEMO. With respect ...

Iop Publishing Ltd2017

Improved detection sensitivity for heavy trace elements using a miniature laser ablation ionisation mass spectrometer

Herbert Shea, Reto Wiesendanger, Peter Wurz

Laser ablation ionisation time-of-flight mass spectrometry is a versatile technique to obtain highly sensitive measurement of the elements and isotope composition of solid materials. Because of the measurements of nearly all elements in the sample, large i ...

2017

Probing ice VII crystallization from amorphous NaCl-D2O solutions at gigapascal pressures

Livia Eleonora Bove Kado

We probe the possible inclusion of salt (NaCl) in the ice VII lattice over the pressure range from 2 to 4 gigapascal. We combine data from neutron diffraction experiments under pressure and from computational structure searches based on density functional ...

Royal Soc Chemistry2017

Synthetic NPA diagnostic for energetic particles in JET plasmas

Henri Weisen

Neutral particle analysis (NPA) is one of the few methods for diagnosing fast ions inside a plasma by measuring neutral atom fluxes emitted due to charge exchange reactions. The JET tokamak features an NPA diagnostic which measures neutral atom fluxes and ...

Iop Publishing Ltd2017

Using SAS functions and high-resolution isotope data to unravel travel time distributions in headwater catchments

Andrea Rinaldo, Paolo Benettin, Gianluca Botter

We use high-resolution tracer data from an experimental site to test theoretical approaches that integrate catchment-scale flow and transport processes in a unified framework centered on selective age sampling by streamflow and evapotranspiration fluxes. T ...

American Geophysical Union2017

Oxaliplatin reacts with DMSO only in the presence of water

Paul Joseph Dyson, Laure Menin, Hristo Plamenov Varbanov

Herein we show that oxaliplatin reacts rapidly with DMSO in aqueous solutions, despite being stable in pure DMSO and pure water. Furthermore, the reactivity of the clinically applied Pt(II) drugs in water/DMSO and PBS/DMSO mixtures, and the nature of the s ...

2017

Search for Heavy Right Handed Neutrinos at the FCC-ee

Elena Graverini

The Standard Model of particle physics is still lacking an understanding of the generation and nature of neutrino masses. A favorite theoretical scenario (the see-saw mechanism) is that both Dirac and Majorana mass terms are present, leading to the existen ...

Elsevier Science Bv2016

Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water

Michele Ceriotti, Sylvie Roke, Carlos Alberto Macias Romero, Yixing Chen, Halil Ibrahim Okur, David Mark Wilkins, Gabriele Tocci, Chung-Wen Liang, Nikolaos Gomopoulos

Electrolytes interact with water in many ways: changing dipole orientation, inducing charge transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous experiments and computations have detected short-range perturbations that ...

American Association for the Advancement of Science (AAAS)2016

Experimental and Theoretical Studies of Low-Energy Penning Ionization of NH3, CH3F, and CHF3

Andreas Osterwalder, Justinas Jankunas

We present results from a joint theoretical and experimental study of the low-energy Penning ionization of NH3, CH3F, and CHF3 by metastable Ne(P-3(2)) and He(S-3(1)) atoms. We combine the merged neutral beams experiment, covering a range of collision ener ...

Wiley-Blackwell2016

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