The silver aluminates AgAl[OC(CF3)2(R)]4 (R = H, CH3, CF3) react with solns. of white phosphorus P4 to give complexes that bind one or two almost undistorted tetrahedral P4 mols. in an h2 fashion: [Ag(P4)2]+[Al(OC(CF3)3)4]- (1) contg. the 1st homoleptic me ...
2002