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The synthesis and characterization of a series of cobalt(III) complexes of the general type Co(N2O2)(L-2) are described. The N2O2 Schiff base ligands used are Me-salpn (H2Me-salpn = N,N'-bis(methylsalicylidene)-1,3-propylenediamine) (1-3) and Me-salbn ...
A thin aqueous film prepared by layer-by-layer assembly of oppositely charged polypeptides on 4-aminobenzoic acid modified porous reticulated vitreous carbon (RVC) electrodes was used with the aim of forming a 3D-ITIES. The film containing a redox mediator ...
Three substituted-pyridyl functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) derivatives 1-3 and their corresponding Ni(II) and Co(II) complexes have been synthesized and characterized. Their electrochemical properties in CH2Cl2 solution have ...
Machining with electrochemical discharges is an unconventional technology able to machine several electrically non-conductive materials like glass or some ceramics. After almost 40 years of its first mention in literature, this technology remains an academ ...
The aim of this work was to develop new, organic dyes, capable of harvesting photons in the red to near-IR region of the spectrum. A series of squaraine and tricarbocyanine dyes were produced and characterised and their optical and redox properties studied ...
DNA functionalised semiconductor metallic oxide electrodes have been developed for the direct electrochemical detection of DNA hybridization, without labelling or the introduction of a redox couple. Conductive CdIn2O4 thin films with controlled properties ...
TiO2/ITO modified electrodes were developed to quantitatively photooxidize adsorbed ds-DNA and to study the effect of antioxidants as ds-DNA protecting agents. TiO2 films are used for efficient ds-DNA immobilization, for ds- DNA oxidation through photogene ...
This paper describes the characterization and application of electrically insulated conductive tips mounted on a cantilever for use in an atomic force microscope and operated in liquid. These multifunctional probes were microfabricated and designed for mea ...
Under gas evolution, the current voltage characteristics of an electrochemical cell are strongly affected by the presence of growing bubbles. At high current densities, the evolution of the bubbles becomes the rate limiting step of the electrochemical proc ...
The pi-stacking between aromatic oligomers has been extensively studied for many years, although the notion of exploiting this phenomenon as the driving force for molecular actuation has only recently emerged. In this work we examine with MP2 and Car-Parri ...
