Concept

Géométrie moléculaire plane trigonale

Publications associées (36)

Significant Improvement of Dye-Sensitized Solar Cell Performance by Small Structural Modification in π-Conjugated Donor-Acceptor Dyes

Shaik Mohammed Zakeeruddin, Jacques-Edouard Moser, Robin Humphry-Baker, Joël Teuscher, Magdalena Anna Marszalek, Mateusz Barnaba Wielopolski, Amaresh Mishra

Two donor-π-acceptor (D-π-A) dyes are synthesized for application in dye- sensitized solar cells (DSSC). These D-π-A sensitizers use triphenylamine as donor, oligothiophene as both donor and π-bridge, and benzothiadiazole (BTDA)/cyanoacrylic acid as accept ...

Wiley-Blackwell2012

Facile fabrication of nanofluidic diode membranes using anodic aluminium oxide

Jürgen Brugger, Philippe Renaud, Arnaud Bertsch, Fabien Patrick Wildhaber, Songmei Wu, Oscar Vazquez Mena

Active control of ion transport plays important roles in chemical and biological analytical processes. Nanofluidic systems hold the promise for such control through electrostatic interaction between ions and channel surfaces. Most existing experiments rely ...

Royal Soc Chemistry2012

DNA Reactivity Profile of trans-Platinum Planar Amine Derivatives

Alexey Nazarov

New trans-platinum planar amines (TPAs) represent a family of platinum-based drugs with cytotoxicity equivalent to that of cisplatin, but with negligible cross-resistance. According to the substitution pattern around the metal center, distinct DNA adducts ...

2011

The biphenyl-monitored effective size of unsaturated functional or fluorinated ortho substituents

The size of a series of typical substituents has been probed by dynamic NMR measurements of the barriers to aryl-aryl rotation of the corresponding biphenyls. The resulting B values are meaningful because only mono-ortho substituted compounds were investig ...

2010

Role of Adsorbed H, C, O, and CO on the Atomic Structure of Free and MgO(100)-Supported Ir-4 Clusters: An ab Initio Study

Zeljko Sljivancanin, Alfonso Baldereschi, Vladan Stevanovic

We applied density functional theory based on ultrasoft pseudopotentials to study the structural properties of Ir-4 clusters both in the gas phase and adsorbed on a MgO(100) surface. To resolve the discrepancy between experimental data which suggest a tetr ...

2010

Intermolecular Interactions as Actors in Energy-Transfer Processes in Lanthanide Complexes with 2,2′-Bipyridine

Jean-Claude Bünzli

A series of lanthanide complexes [LnClx(bpy)y(H2O)z]Cl3-x(H2O)n(EtOH)m (Ln ) Eu, Gd, Tb; x ) 1, 2; y ) 1, 2; z ) 2-4) with different numbers of 2,2′-bipyridine (bpy), chloride ions, and water molecules in the inner coordination sphere were synthesized and ...

2009

What governs nitrogen configuration in substituted aminophosphines?

Matthew Wodrich, Pierre-Yves Morgantini

The trigonal planar geometry of the nitrogen atom in commonly used phosphoramidite ligands is not in line with the traditional valence shell electron pair repulsion (VSEPR) model. In this work, the effects governing nitrogen configuration in several substi ...

2008

Electronic Structure of Surface-supported Bis(phthalocyaninato) terbium(III) Single Molecular Magnets

Klaus Kern

The electronic structure of isolated bis(phthalocyaninato) terbium(ill) molecules, a novel single-molecular-magnet (SMM), supported on the Cu(111) surface has been characterized by density functional theory and scanning tunneling spectroscopy. These studie ...

2008

The role of nanostructure in the wetting behavior of mixed-monolayer-protected metal nanoparticles

Nicola Marzari, Francesco Stellacci, Munish Sharma

Self-assembled monolayer-protected nanoparticles are promising candidates for applications, such as sensing and drug delivery, in which the molecular ligands' interactions with the surrounding environment play a crucial role. We recently showed that, when ...

2008

Experimental study of electrical breakdown in MEMS devices with micrometer scale gaps

Philippe Renaud, Herbert Shea

We present an experimental study of the DC breakdown voltage of MEMS interdigitated aluminum electrodes with gaps ranging from 10 to 500 µm. Unlike most research on MEMS electrodes, that was done at atmospheric pressure, our work has focused on the effect ...

2008

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