Premier principe de la thermodynamique

Résumé

Selon le premier principe de la thermodynamique, lors de toute transformation, il y a conservation de l'énergie. Dans le cas des systèmes thermodynamiques fermés, il s'énonce de la manière suivante : Au cours d'une transformation quelconque d'un système fermé, la variation de son énergie est égale à la quantité d'énergie échangée avec le milieu extérieur, par transfert thermique (chaleur) et transfert mécanique (travail). Premier principe de la thermodynamique Énoncé Pour tout système thermodynamique, on peut définir, à une constante près, une fonction U, appelée énergie interne, et ayant les propriétés suivantes :

U est une fonction d'état (elle ne dépend que des états initiaux et finaux de la transformation) ;
U est extensive ;
U se conserve dans un système isolé. La variation de U au cours d'une transformation infinitésimale d'un système fermé (de composition fixe) vérifie :

\mathrm{d}E_\mathrm{c} + \mathrm{d}E_\mathrm{p} +

Source officielle

https://fr.wikipedia.org/wiki/Premier_principe_de_la_thermodynamique

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Eukaryotic organisms play an important role in industrial biotechnology, from the production of fuels and commodity chemicals to therapeutic proteins. To optimize these industrial systems, a mathematical approach can be used to integrate the description of multiple biological networks into a single model for cell analysis and engineering. One of the most accurate models of biological systems include Expression and Thermodynamics FLux (ETFL), which efficiently integrates RNA and protein synthesis with traditional genome-scale metabolic models. However, ETFL is so far only applicable for E. coli. To adapt this model for Saccharomyces cerevisiae, we developed yETFL, in which we augmented the original formulation with additional considerations for biomass composition, the compartmentalized cellular expression system, and the energetic costs of biological processes. We demonstrated the ability of yETFL to predict maximum growth rate, essential genes, and the phenotype of overflow metabolism. We envision that the presented formulation can be extended to a wide range of eukaryotic organisms to the benefit of academic and industrial research. Formulating metabolic networks mathematically can help researchers study metabolic diseases and optimize the production of industrially important molecules. Here, the authors propose a framework that allows to model eukaryotic metabolism considering gene expression and thermodynamic constraints.

NATURE PORTFOLIO2021

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The absence of general theoretical models describing linear sweep voltammetry (LSV) or cyclic voltammetry (CV) responses for soluble-insoluble systems such as one-step electrodeposition reactions under quasi-reversible condition makes it difficult to extract quantitative kinetic information from experimental voltammograms. In this work, a semi-analytical method for modelling LSV responses for one–step electrodeposition process is described, for a case where instantaneous nucleation takes place, such as metal deposition on same metal. Voltammetric peaks were analyzed following variation of both dimensionless rate constants and charge transfer coefficients in a broad range. Therefore, kinetic curves for electron transfer processes were established and fitted perfectly by sigmoidal Boltzmann function and linear models. With these models, LSV or CV experimental data can be used to measure electrodeposition reactions kinetics whatever the degree of reversibility. The Cu(I)/Cu(0) couple in acetonitrile was selected as an experimental example. The model developed in this work predicts accurately the current response for Cu electrodeposition reaction and an excellent experiment–theory agreement was found.

2018

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The substitution of CFC refrigerants in refrigeration systems, heat pumps and organic Rankine cycles for heat recovery, requires good methods for predicting heat transfer of substitute fluids. The measurements in the LENI test facility (concentric tubes with water flowing in a countercurrent flow) with HFC 407C, HFC 134a, HCFC 123, HFC 404A and HFC/HCFC 402A provide a new data band for new refrigerants, and allow a coherent comparison with old refrigerants CFC 11, CFC 12, CFC/HCFC 502 and with existing correlations. The existing correlations were found to be inadequate. Because of this work, an improved flow pattern map and flow boiling model were developed, which resulted in a substantial progress in the accurate predict of heat transfer in plain, horizontal tubes for refigerants without oil. The Kattan et al. (1996, [6]) correlation was programmed to calculate and compare predicted heat transfer coefficients to the new HFC 407C test data. The flow pattern map proposed by Kattan et al. (1996) was also programmed and compared to flow regimes observed for HFC 407C. It predicted the HFC 407C flow pattern data quite accurately. The original objective of the HFC 407C measurements was the validation of the Kattan et al. (1996) correlation applied to a zeotropic refrigerant blend. Local flow boiling heat transfer coefficients were measured for HFC 407C evaporating inside a microfin and plain tube. In addition, microfin heat transfer augmentation relative to a plain tube was investigated. The presence of oil in the evaporator had a complex effect on heat transfer coefficients. Local flow boiling heat transfer coefficients were measured for refrigerant HFC 407C ester oil mixtures (Mobil EAL Arctic 68). A new thermodynamic approach for modeling mixtures of zeotropic refrigerant blends and lubricating oils was also developed. A very high accuracy, straight vibrating tube type of density flowmeter was used to measure oil concentrations of flowing HFC 407C oil mixtures. The test covered oil concentration from 0.5-5 wt.% oil. A method was proposed to predict thermodynamic and transport properties of the refrigerant-oil mixtures. In addition, a first empirical approach was proposed for predicting heat transfer for boiling of refrigerant-oil mixtures. Based on this work, the following phenomena important to the problem were identified that require further investigation: • oil retention in the evaporator tubes that was found and clearly proved in the present project. • the formation of foam in the HFC 407C/oil mixture (but not in the previous HFC 134a/oil tests) •the effect of oil on flow patterns, in particular stratified and stratified-wavy flows.

1996

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1996