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Premier principe de la thermodynamique

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Hydrogen production on demand by redox-mediated electrocatalysis: A kinetic study

Hubert Girault, Sunny Isaïe Maye, Danick Reynard

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety, membrane degradation, purity and flexibility. Herein, vanadium-mediated hydrogen ...

ELSEVIER SCIENCE SA2021

Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds

Athanasios Nenes

The acidity of aqueous atmospheric solutions is a key parameter driving both the partitioning of semi-volatile acidic and basic trace gases and their aqueous-phase chemistry. In addition, the acidity of atmospheric aqueous phases, e.g., deliquesced aerosol ...

Copernicus GmbH2021

From the Principle of Inertia to the Death Drive: The Influence of the Second Law of Thermodynamics on the Freudian Theory of the Psychical Apparatus

Pierre Magistretti, Jean-Philippe Ansermet

In the Freudian theory of the psychical apparatus, the introduction from the 1920s onward of the second drive dualism appears as a major turning point. The idea of a "death drive," first expressed in Beyond the Pleasure Principle (Freud, 1920), is generall ...

Frontiers Media2020

Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Cristian Pezzato

A major goal in the design of synthetic molecular machines is the creation of pumps that can use the input of energy to transport material from a reservoir at low chemical potential to a different reservoir at higher chemical potential, thereby forming and ...

ROYAL SOC CHEMISTRY2020

The ETFL formulation allows multi-omics integration in thermodynamics-compliant metabolism and expression models

Vassily Hatzimanikatis, Pierre Guy Rémy Salvy

Systems biology has long been interested in models capturing both metabolism and expression in a cell. We propose here an implementation of the metabolism and expression model formalism (ME-models), which we call ETFL, for Expression and Thermodynamics Flu ...

Nature Research2020

Development of collapse-consistent loading protocols for experimental testing of steel columns

Dimitrios Lignos

In order to effectively utilize results from quasi-static cyclic testing on structural components for the earthquake-induced collapse risk quantification of structures, the need exists to establish collapse-consistent loading protocols representing the asy ...

2020

Synthesis of grid compliant substitute natural gas from a representative biogas mixture in a hybrid Ni/Ru catalysed reactor

Andreas Züttel, Emanuele Moioli, Robin Tobias Andreas Mutschler, Marco Calizzi, Alexandre Borsay

We demonstrate biogas upgrading towards full CO2 conversion in mild conditions in a three-step reactor system using Ru- and Ni-based catalysts. In each of the three reactor stages, the temperature is carefully controlled, thus optimizing the reaction therm ...

2020

Version 1 of a sea ice module for the physics-based, detailed, multi-layer SNOWPACK model

Michael Lehning, Katherine Colby Leonard, Nander Wever

Sea ice is an important component of the global climate system. The presence of a snowpack covering sea ice can strongly modify the thermodynamic behavior of the sea ice, due to the low thermal conductivity and high albedo of snow. The snowpack can be stra ...

COPERNICUS GESELLSCHAFT MBH2020

Effect of Fluid Viscosity on Earthquake Nucleation

Marie Estelle Solange Violay, Chiara Cornelio

Injection of fluids in geo-reservoirs can reduce the effective stresses at depth, lubricating the nearby faults, promoting slip and, potentially, earthquakes. High-viscous fluids are often used during hydraulic fracturing and production phases in geo-reser ...

2020

Ubiquitous aluminium contamination in water and amyloid hybrid membranes as a sustainable possible solution

Francesco Stellacci, Raffaele Mezzenga, Malvina Julia Ida Pauchard

We develop a membrane technology based on amyloid fibrils to remove aluminium from water and minimize its exposure to humans. We study aluminium adsorption by amyloid fibrils by evaluating the binding isotherms, the thermodynamics and the effects of differ ...

Royal Society of Chemistry2019

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From the Principle of Inertia to the Death Drive: The Influence of the Second Law of Thermodynamics on the Freudian Theory of the Psychical Apparatus

Pierre Magistretti, Jean-Philippe Ansermet

Frontiers Media2020

Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Cristian Pezzato

ROYAL SOC CHEMISTRY2020

Development of collapse-consistent loading protocols for experimental testing of steel columns

Dimitrios Lignos

2020

Synthesis of grid compliant substitute natural gas from a representative biogas mixture in a hybrid Ni/Ru catalysed reactor

Andreas Züttel, Emanuele Moioli, Robin Tobias Andreas Mutschler, Marco Calizzi, Alexandre Borsay

2020