Publications associées (72)

The Use of Metal-Organic Frameworks as Adsorbents for Hydrogen Purification

Berend Smit

Metal-organic frameworks of the family M2 (2,5-dioxido-1,4-benzenedicarboxylate) wherein M=Mg, Mn, Fe, Co, Cu, Ni or Zn are a group of porous crystalline materials formed of metal cations or clusters joined by multitopic organic linkers that can be used to ...
2011

A micro gas preconcentrator with improved performance for pollution monitoring and explosives detection

Nico de Rooij, Danick Briand, El Hadji Malick Camara

This paper presents the optimization of a micro gas preconcentrator based on a micro-channel in porous and non-porous silicon filled with an adequate adsorbent. This micro gas preconcentrator is both applicable in the fields of atmospheric pollution monito ...
Elsevier2011

Method For Predicting Adsorbent Performance

Berend Smit

A method for predicting selective performance of an adsorbent is disclosed. The adsorbent is selected from a list of metals and/or metal cations for use in removing contaminants as thiophene derivatives in hydrocarbon feed. The metals or metal cations are ...
2011

Control of morphology and nanostructure of copper and cobalt oxalates: Effect of complexing ions, polymeric additives and molecular weight

Heinrich Hofmann, Paul Bowen, Jacques Lemaître, Alke Fink, Nathalie Jongen

Precipitated oxalates are often nanostructured and can be used as precursors for nanostructured oxides for different applications. The modification of the particle shape and nanostructures of both copper and cobalt oxalates has been demonstrated using poly ...
2010

Molecular Simulation Studies of Separation of CO2/N-2, CO2/CH4, and CH4/N-2 by ZIFs

Berend Smit

In this work, molecular simulations were performed to evaluate the separation performance of two typical zeolitic imidazolate frameworks (ZIFs), ZIF-68 and ZIF-69, for CO2/N2, CO2/CH 4, and CH4/N2 mixtures. To do this, we first identified a suitable force ...
2010

Enhanced ammonia oxidation on BDD induced by inhibition of oxygen evolution reaction

Christos Comninellis, Agnieszka Kapalka, Nina-Luisa Michels

Electrochemical oxidation of ammonia (NH3 and NH4+) on boron-doped diamond (BDD) electrode was studied using differential electrochemical mass-spectrometry (DEMS) and chronoamperometry. Electro-oxidation of ammonia induces inhibition of the oxygen evolutio ...
Elsevier2010

Postpolymerization modification of poly(pentafluorophenyl methacrylate): Synthesis of a diverse water-soluble polymer library

Harm-Anton Klok, Matthew Gibson

This article explores the feasibility of poly(pentafluorophenyl methacrylate) (PPFMA) prepared by reversible addition fragmentation chain transfer (RAFT) polymerization as a platform for the preparation of diverse libraries of functional polymers via postp ...
2009

Separation properties of supported ionic liquid-polydimethylsiloxane membrane in pervaporation process

Zhaofu Fei

Pervaporation separation properties of water-butan-l-of binary mixtures were measured with the use of three supported liquid membranes at 37 C, namely PDMS, 1-ethenyl-3-ethyl-imidazolium hexafluorophosphate-PDMS, and tetrapropyl-ammonium tetracyanoborate-P ...
2009

Stabilization of bimolecular islands on ultrathin NaCl films by a vicinal substrate

Harald Brune, Marta Canas Ventura

The structure of ultrathin NaCl films on Au(1 1 1) and on Au(11 12 12), as well as the one of bimolecular 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) and 1,4-bis-(2,4-diamino-1,3,5,-triazine)-benzene (BDATB) islands on NaCl films on both surfaces have ...
Elsevier2009

Bead-based single protein micro-array realized through electrostatic self-assembly of carboxylated beads

Martinus Gijs, Abdeljalil Sayah, Venkataragavalu Sivagnanam

We report here a simple method, based on electrostatic self-assembly, for realizing bead-based single protein micro-arrays. We generate positively charged surface micro-patterns on a glass substrate and use them as template for adsorbing negatively-charged ...
2008

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