Cycle du fer

The iron cycle (Fe) is the biogeochemical cycle of iron through the atmosphere, hydrosphere, biosphere and lithosphere. While Fe is highly abundant in the Earth's crust, it is less common in oxygenated surface waters. Iron is a key micronutrient in primary productivity, and a limiting nutrient in the Southern ocean, eastern equatorial Pacific, and the subarctic Pacific referred to as High-Nutrient, Low-Chlorophyll (HNLC) regions of the ocean. Iron exists in a range of oxidation states from -2 to +7; however, on Earth it is predominantly in its +2 or +3 redox state and is a primary redox-active metal on Earth. The cycling of iron between its +2 and +3 oxidation states is referred to as the iron cycle. This process can be entirely abiotic or facilitated by microorganisms, especially iron-oxidizing bacteria. The abiotic processes include the rusting of iron-bearing metals, where Fe2+ is abiotically oxidized to Fe3+ in the presence of oxygen, and the reduction of Fe3+ to Fe2+ by iron-sulfide minerals. The biological cycling of Fe2+ is done by iron oxidizing and reducing microbes. Iron is an essential micronutrient for almost every life form. It is a key component of hemoglobin, important to nitrogen fixation as part of the Nitrogenase enzyme family, and as part of the iron-sulfur core of ferredoxin it facilitates electron transport in chloroplasts, eukaryotic mitochondria, and bacteria. Due to the high reactivity of Fe2+ with oxygen and low solubility of Fe3+, iron is a limiting nutrient in most regions of the world. On the early Earth, when atmospheric oxygen levels were 0.001% of those present today, dissolved Fe2+ was thought to have been a lot more abundant in the oceans, and thus more bioavailable to microbial life. Iron sulfide may have provided the energy and surfaces for the first organisms. At this time, before the onset of oxygenic photosynthesis, primary production may have been dominated by photo-ferrotrophs, which would obtain energy from sunlight, and use the electrons from Fe2+ to fix carbon.

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The Mononuclear Metal-Binding Site of Mo-Nitrogenase Is Not Required for Activity

Wenyu Gu

The biological N-2-fixation process is catalyzed exclusively by metallocofactor-containing nitrogenases. Structural and spectroscopic studies highlighted the presence of an additional mononuclear metal-binding (MMB) site, which can coordinate Fe in additio ...

Washington2023

Multiphase processes in the EC-Earth model and their relevance to the atmospheric oxalate, sulfate, and iron cycles

Athanasios Nenes

Understanding how multiphase processes affect the iron-containing aerosol cycle is key to predicting ocean biogeochemistry changes and hence the feedback effects on climate. For this work, the EC-Earth Earth system model in its climate-chemistry configurat ...

COPERNICUS GESELLSCHAFT MBH2022

Valorisation of locally available clays for producing blended cements is crucial for a widespread adoption of sustainable binders incorporating these materials. In some places, clays can be intermixed with small amounts of iron sulfides, which could eventu ...

SPRINGER2022

Lithotroph

Lithotrophs are a diverse group of organisms using an inorganic substrate (usually of mineral origin) to obtain reducing equivalents for use in biosynthesis (e.g., carbon dioxide fixation) or energy conservation (i.e., ATP production) via aerobic or anaerobic respiration. While lithotrophs in the broader sense include photolithotrophs like plants, chemolithotrophs are exclusively microorganisms; no known macrofauna possesses the ability to use inorganic compounds as electron sources.

Oxyde de fer

200px|vignette|Poudre d'hématite . La couleur brune rougeâtre indique que le fer est à l'état d'oxydation +III. Un oxyde de fer est un composé chimique résultant de la combinaison d'oxygène et de fer. Les oxydes de fer sont abondants dans la nature, soit dans des roches, notamment minerai de fer, soit dans les sols. Les oxydes de fer, surtout synthétiques, servent soit comme pigments, soit pour leurs propriétés magnétiques.

Biogéochimie

vignette|Biogeochimie La biogéochimie est l'étude du processus cyclique de transfert des éléments chimiques de l'environnement à partir des milieux abiotiques vers les organismes qui à leur tour retransmettent ses constituants à l'environnement. (Traduction française de l'article d'Odum, 1971) Cette notion a été « inventée » par le savant russe Vladimir Vernadski. Différentes analyses moléculaires permettent de qualifier le caractère biogéochimique de la matière organique comme l'analyse des sucres, des lipides, des phénols de la lignine.

ENV-202: Microbiology for engineers

"Microbiology for engineers" covers the main microbial processes that take place in the environment and in treatment systems. It presents elemental cycles that are catalyzed by microorganisms and that

Oxydation du fer : processus et mécanismes ENV-202: Microbiology for engineers

Explore le processus d'oxydation du fer, couvrant les mécanismes d'oxydation abiotiques et microbiens, la diversité microbienne et l'importance écologique.

Réduction microbienne du fer MOOC: Water quality and the biogeochemical engine

Déplacez-vous dans la réduction microbienne du fer, les micro-organismes réducteurs du fer et leur importance écologique.

L'oxydation du fer microbienne : processus et mécanismes MOOC: Water quality and the biogeochemical engine

Déplacez-vous dans les processus d'oxydation du fer microbien, les mécanismes et l'importance écologique dans le contrôle de la biodisponibilité du fer.