Véhicule à hydrogène | EPFL Graph Search

Un véhicule à hydrogène est un moyen de transport qui utilise une transformation chimique du dihydrogène comme énergie de propulsion. En particulier, on appelle voiture à hydrogène un véhicule à propulsion électrique muni d'une pile à combustible utilisant le plus souvent l'hydrogène comme combustible réducteur. C'est un type particulier de véhicule à pile à combustible. Cette appellation englobe des véhicules du domaine de l'aérospatiale (comme les fusées) ou du domaine militaire (comme des sous-marins à hydrogène), bien que l'usage courant renvoie plutôt au monde des transports. Le véhicule à hydrogène est souvent présenté comme « décarboné » car sa motorisation n'émet pas directement de gaz à effet de serre. Toutefois, la production préalable de l'hydrogène consommé est encore à plus de 99 % réalisée à partir d'hydrocarbures en 2021, dont les fuites de méthane contribuent à l'effet de serre. Il est également possible de produire l'hydrogène par électrolyse de l'eau en exploitant d

Delayed Hydride Cracking in Irradiated and Unirradiated Zircaloy-2 Cladding

Aaron William Colldeweih

Zirconium alloys used in the nuclear industry are exposed to extreme conditions undergoing high levels of irradiation damage and corrosion. Zircaloy-2 is used as nuclear fuel cladding in boiling water reactors and for the encapsulation of the spallation target in the neutron source SINQ at the Paul Scherrer Institute. As a result of oxidation, hydrogen is produced and partially taken up into the zirconium matrix. As the hydrogen reaches the solubility limit, it precipitates in the form of a zirconium hydride. A number of deleterious effects of hydrides have been extensively studied, including the embrittlement of the material and a unique cracking phenomenon, namely delayed hydride cracking (DHC). DHC occurs as hydrogen in solid solution diffuses towards locations of higher tensile stress, where it subsequently precipitates as the local solvus limit is reached. Once the hydride grows to a critical size, it fractures, which can continue to propagate in repeated steps by the same mechanism.Several studies have been performed in order to understand properties of DHC based on parameters like, alloy type, cracking temperature, hydrogen content, and cracking direction. The most important mechanical properties include the fracture toughness and cracking velocity, which governs the material failure conditions. Crystallographic properties have been investigated in order to understand how complex hydride precipitation develops within the context of DHC conditions. In this project, radial DHC is explored in irradiated and unirradiated thin-walled Zircaloy-2 nuclear fuel cladding with and without an inner liner, in addition to spallation target rod material. A unique three-point bending test, applicable also for irradiated samples in the hotlab, was developed to induce a consistent radially propagating outside-in crack. Results have provided insight into the effects of the inner liner on cracking velocity, showing correlations with the hydrogen depletion. The combined DHC and creep mechanisms, which cannot be decoupled, is coined as âcreep-delayed hydride crackingâ. As the initiating conditions for DHC are of great technical importance, the threshold stress intensity factor has been investigated, under ideal DHC conditions, where a minimum value occurs around 6 MPaâm. Quantitative analysis of the hydrogen distribution around the tip of an arrested DHC crack tip has been performed with neutron radiography at the SINQ. Trends show that the hydrogen concentration around the crack tip increases with temperature resulting likely from the larger hydrogen diffusion, and that the liner reduces the hydrogen available for DHC. Crystallographic analysis has provided insight on the hydride phases responsible for DHC with synchrotron micro X-ray diffraction, performed at the Swiss Light Source at PSI. The results directly suggest that the Î³-hydride is a stable phase precipitated at low temperatures. Testing of irradiated material provided insight into the crack initiation of DHC as a result of the strongly irregular outer surface generated from the oxidation. The propagation pattern is highly irregular compared to the unirradiated material due to the embrittled nature of the cladding from irradiation damage.

EPFL2022

Study of hydrogen storage and compression

Nicolas Jean Matet

The goal of this rapport is to present an overview of the different hydrogen storage technologies, currently available for industrial application or at earlier stages of development. In order to identify the water and mechanical work requirements for compression of hydrogen, flow sheets of several compression process are realized. In order to decrease the work needed for hydrogen compression, realizing part of the compression with a metal-hydride compressor and integrating the compression process with a solar hydrogen production plant was study. It shows that metal-hydride pre-compression of hydrogen using waste heat before mechanical compression has the potential to lower the mechanical work consumption by about 15%compared to multi-stage mechanical compression alone.

2014

Decreasing the Stability of Borohydride with Ionic Liquids for Hydrogen Storage and Carbon Dioxide Conversion

Loris Giovanni Lombardo

The world needs to move from a fossil fuel to a renewable energy based society. With the increasing electricity production from wind and PV, short and long term energy storage are becoming one of challenge of the 21st century. While batteries are the preferred method for short term storage, another technology is required for seasonal storage. Hydrogen is a valuable energy carrier owning its high energy density (122 kJ/g). However, compact and safe storage of H2 is challenging. The current solution is to compress hydrogen up to 700 bar for mobile application (fuel cell cars), and metal hydrides for stationary application. Material-based H2 storage avoids using high-pressure cylinder. Complex hydrides are especially attractive for solid-state H2 storage due to their high gravimetric and volumetric hydrogen density. Sodium borohydride (NaBH4) contains 10.6 mass% of H2, but high temperatures are needed to release H2 (505 Â°C) and the reaction is not reversible under moderate conditions. To apply complex hydrides in real applications, they must be modified to improve the kinetics and thermodynamics of H2 desorption. Several possibilities exist such as confinement into scaffolds, catalyst addition, or combination of several hydrides to modify the dehydrogenation pathway. The stability of complex hydrides is determined by the localization of the charge on the central atom of the complex. Therefore, in this thesis the interaction of highly polar or ionic compounds with complex hydrides were investigated. We combine NaBH4 with a special class of organic salts: ionic liquids (IL). Considering their chemical and thermal stability, IL are attractive additive. Using organic additives instead of expensive metal catalysts is another advantage. Two different techniques were employed to combine the IL and NaBH4. The first one consists of mechanochemically milling them to create an interaction between BH4- and IL. The second one is to directly synthesized IL borohydrides ([IL][BH4]) by metathesis reaction. Different ILs, such as vinylbenzyltrimethylammonium chloride ([VBTMA][Cl]), 1-butyl-3-methylimidazolium chloride ([bmim][Cl]), and 1-ethyl-1-methylpyrrolidinium bromide ([EMPY][Br]) were tested. [bmim][BH4] was able to release H2 below 100 Â°C. The hydrogen content ranges between 2.4 mass% and 2.9 mass%. The second challenge of this century is the CO2 problematic. Atmospheric CO2 concentration linearly increases, leading to greenhouse effect. Carbon capture and sequestration (CCS) and utilization (CCU) are primordial research topic to stabilize the CO2 emission. Hydrides are primary reducing agents, thus reduction of CO2 can be accomplished with them. Direct CO2 reduction at ambient conditions is challenging for classical borohydrides. With our [IL][BH4], gaseous CO2 can be captured and reduced under ambient conditions (1 bar, RT). Three CO2 bounds with boron to give triformatoborohydride ([HB(OCHO)3]â. Dilute CO2 (6 vol%) can be used as well. The reaction was followed in real time with a magnetic suspended balance (MSB). Further, CO2 reduction happened when air is used as a carbon dioxide source. Formic acid can be obtained by adding HCl. Thus, ionic liquid borohydrides have great potential as a CO2 absorber and reducer to alternative fuels. In short, we applied ionic liquid to destabilized borohydrides. The resulting materials exhibited potential for solid-state hydrogen storage, as well as CO2 capture and transformation.

EPFL2021