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Publications associées (609)

On the Modeling of Organic Electrochemical Transistors

Due to their synaptic functionality based on interacting electronic and ionic charge carriers, organic electrochemical transistors (OECTs) appeal as highly attractive candidates for a new generation of organic neuromorphic devices. Despite their acknowledg ...

SPIE-INT SOC OPTICAL ENGINEERING2022

Simultaneous measurements of unstable and stable Alfven eigenmodes in JET

Ambrogio Fasoli, Mario Ludovico Podesta

In this paper, we report the novel experimental observation of both unstable and stable toroidicity-induced Alfven eigenmodes (TAEs) measured simultaneously in a JET tokamak plasma. The three-ion-heating scheme (D-DNBI-He-3) is employed to accelerate deute ...

IOP Publishing Ltd2022

Two-Carbon Ring Expansion of Cyclobutanols to Cyclohexenones Enabled by Indole Radical Cation Intermediate: Development and Application to a Total Synthesis of Uleine

Qian Wang, Jieping Zhu, Alexandre Julien Florent Leclair

A single-electron transfer (SET) oxidation of indole or benzo[b]thiophene to a radical cation reverses the intrinsic polarity of these pi-excessive bicyclic heteroarenes. Here we report an oxidative two-carbon homologation of cyclobutanols to cyclohexenone ...

AMER CHEMICAL SOC2022

Coincidence imaging spectroscopy of extreme-ultraviolet photoionisation processes in molecules and clusters

Andrew Daniel Bonnar Clark

Presented here is the design, construction and commissioning of a coincidence imaging spectroscopy endstation coupled to the Harmonium high-harmonic generation (HHG) extreme-ultraviolet photon source at the Lausanne Centre for Ultrafast Science. The endsta ...

EPFL2021

Metal-Stabilized Boronate Ester Cages

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Erica Giraldi

Molecular cages with arylboronate ester caps at the vertices are described. The cages were obtained by metal-templated polycondensation reactions of a tris(2-formylpyridine oxime) ligand with arylboronic acids. Suited templates are triflate or triflimide s ...

2021

Coating Porous MXene Films with Tunable Porosity for High-Performance Solid-State Supercapacitors

Jakob Heier, Sina Abdolhosseinzadeh

Two-dimensional MXenes with their outstanding physical and chemical properties have been extensively used in numerous fields such as electrochemical energy storage, catalysis, and sensing. In these applications, high active surface area and facilitated dif ...

WILEY-V C H VERLAG GMBH2021

Negative hydrogen ion dynamics inside the plasma volume of a linear device: Estimates from particle-in-cell calculations

Ivo Furno, Alan Howling, Philippe Frédérique Bruno Guittienne, Rémy Jacquier, Riccardo Agnello

Negative hydrogen or deuterium ions are the precursor particles used to generate a high power beam of neutrals in order to heat the tokamak plasma core of magnetic fusion devices, inject current, and to some extent control instabilities. In the case of ITE ...

AIP Publishing2021

Half-clathrochelate Complexes as Versatile Links in Supramolecular Chemistry

Erica Giraldi

Clathrochelate complexes have been widely investigated with different size and shape and used as building blocks for the obtainment of discrete supramolecular architectures. These clathrochelate complexes are very stable and kinetically inert complexes. A ...

EPFL2021

Revisiting Cation Complexation and Hydrogen Bonding of Single-Chain Polyguluronate Alginate

Modifying the properties of bio-based materials has garnered increasing interest in recent years. In related applications, the ability of alginates to complex with metal ions has been shown to be effective in liquid-to-gel transitions, useful in the develo ...

2021

How natural materials remove heavy metals from water: mechanistic insights from molecular dynamics simulations

Wanda Andreoni, Fabio Pietrucci

Water pollution by heavy metals is of increasing concern due to its devastating effects on the environment and on human health. For the removal of heavy metals from water sources, natural materials, such as spent-coffee-grains or orange/banana/chestnut pee ...

2021

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