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Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln(IV) were known only for cerium and more recently terbium. Here we demonstrate that the +IV oxidation state is also accessible for the large praseodymium (Pr) cation. The oxidation of the tetraki ...
While we fundamentally understand the dynamics of simple cracks propagating in brittle solids within perfect (homogeneous) materials, we do not understand how paths of moving cracks are determined. We experimentally study strongly perturbed cracks that pro ...
The bidentate carboxamide ligand N-(thiazole-2-yl) picolinamide (LH) was synthesized in the environmentally friendly ionic liquid TBAB, and the five-coordinated Cu-II-complex, [Cu(L)(2)(H2O)]center dot CHCl3 (1) was synthesized from LH and copper(II)acetat ...
Superior stability and safety are key promises attributed to all-solid-state batteries (ASSBs) containing solid-state electrolyte (SSE) compared to their conventional counterparts utilizing liquid electrolyte. To unleash the full potential of ASSBs, SSE ma ...
Carbonaceous nanocoatings such as diamond-like amorphous carbon or graphene layers exhibit remarkable properties in multiple fields, ranging from corrosion protection to electronics and lubrication. However, they are typically deposited from the vapor phas ...
Electronic devices are evolving from rigid devices into flexible and stretchable structures, enabling a seamless integration of electronics into our everyday lives. The integration of a variety of electronic materials within thermal-drawn fibers has emerge ...
Biocompatibility restrictions have limited the use of magnetic nanoparticles for magnetic hyperthermia therapy to iron oxides, namely magnetite (Fe3O4) and maghemite (gamma-Fe2O3). However, there is yet another magnetic iron oxide phase that has not been c ...
Heated tipping-bucket (TB) gauges are used broadly in national weather monitoring networks, but their performance for the measurement of solid precipitation has not been well characterized. Manufacturer-provided TB gauges were evaluated at five test sites ...
Electron microscopy offers a wide range of techniques to study materials. Environmental Scanning Electron Microscopy (ESEM), in particular, allows the characterisation of samples at high-temperature using a laser heating stage, and under various gaseous at ...
In this work, we demonstrate that xPb(In1/2Nb1/2)O3-(1-x-y)Pb(Mg1/3Nb2/3)O3-yPbTiO3 [110]-poled domain-engineered relaxor single crystals can be dynamically and reversibly driven through a ferroelectric–ferroelectric phase transition exhibiting a highly en ...
