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Science de la nature
Chimie
Chimie organique
Chimie organométallique

Publications associées (25)

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Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

Andrea Cannizzo, Giulia Fulvia Mancini, Camila Bacellar Cases Da Silveira, Martin Beck, Victoria Kabanova, Samuel Menzi

OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic mul ...

Nature Publishing Group2020

Growth and characterisation of earth-abundant semiconductor nanostructures for solar energy harvesting

Simon Robert Escobar Steinvall

Zinc phosphide (Zn3P2) is a compound semiconductor based on earth-abundant elements with functional properties ideal for solar cell applications. Cheap, abundant, and renewable energy sources are increasingly imperative due to the imminent threat posed by ...

EPFL2020

van der Waals Epitaxy of Earth-Abundant Zn3P2 on Graphene for Photovoltaics

Anna Fontcuberta i Morral, Roland Logé, Cyril Cayron, Elias Zsolt Stutz, Jean-Baptiste Leran, Shreyas Sanjay Joglekar, Mahdi Zamani, Simon Robert Escobar Steinvall, Rajrupa Paul, Nicolas Philippe Laurent Humblot

Earth-abundant semiconducting materials are a potential solution for large-scale deployment of solar cells at a lower cost. Zinc phosphide (Zn3P2) is one such Earth-abundant material with optoelectronic properties suitable for photovoltaics. Herein, we rep ...

2020

The Periodic Table and Kinetics?

André Merbach, Lothar Helm

Mendeleev in his first publication ordered the chemical elements following an apparent periodicity of properties such as atomic volume and valence. The reactivity of the elements was only studied systematically many years later. To illustrate the systemati ...

2019

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone

Here we show that a scaffold combining siloxide ligands and a bridging oxide allows the synthesis and characterization of the stable dinuclear uranium(IV) hydride complex [K-2{U(OSi((OBu)-Bu-t)(3))(3)(mu-O)(mu-H)(2)}], 2, which displays high reductive ...

2019

Discovery of a self-healing catalyst for the hydrolytic dehydrogenation of ammonia borane

Emad Oveisi, Mounir Driss Mensi, Fatmah Ebrahim, Kyriakos Stylianou, Ngoc Tú Nguyên, Andrzej Gladysiak, Bardiya Valizadeh, Fatma Pelin Uran

Sustainable catalysts based on earth-abundant elements are considered as economical alternatives to precious-metal-bearing catalysts and could be impactful for many applications. Self-healing sustainable catalysts, which in addition to their 'green' charac ...

Royal Society of Chemistry2019

A multi-technique approach to study the microstructural properties of tin-based transparent conductive oxides

Federica Landucci

Transparent conductive oxides (TCOs) are semiconductor-like materials that exhibit high electrical conductivity and high optical transparency combined. They are adopted in various applications ranging from gas sensors, to electrochromic windows, to photovo ...

EPFL2019

Multiple morphologies and functionality of nanowires made from earth-abundant zinc phosphide

Anna Fontcuberta i Morral, Elias Zsolt Stutz, Thomas La Grange, Jean-Baptiste Leran, Mahdi Zamani, Simon Robert Escobar Steinvall, Nicolas Tappy, Rajrupa Paul, Reza Zamani

Semiconductors made of earth-abundant elements, such as zinc phosphide, have the potential to substitute less abundant, highly functional compound semiconductors such as InAs or InP. Compound semiconductors in the form of nanowires could revolutionise appl ...

2020

Synthesis and Application of Transition Metal Oxides as Oxygen Evolution Catalysts

Laurent Liardet

Nowadays, mankind is facing an important energy challenge. Depletion in fossil fuels reserves and increasing energy demand, coupled with the problematic greenhouse effect induced by massive anthropogenic release of carbon dioxide into the atmosphere, are d ...

EPFL2019

Intrafascicular electrode implant

Silvestro Micera, Stanisa Raspopovic, Francesco Maria Petrini

An implantable device for intrafascicular stimulation and/or sensing of a peripheral nerve, including a blocking element adapted for wrapping a nerve, comprising an access point and an exit point, and an electrode adapted to traverse the blocking element v ...

2018

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