Concept
Acide acétique
Publications associées (156)
Palladium‐Based Dyotropic Rearrangement Enables A Triple Functionalization of Gem‐Disubstituted Alkenes: An Unusual Fluorolactonization Reaction
Qian Wang, Jieping Zhu, Chenxu Liu, Qiang Feng
We report in this paper a Pd(II)-catalyzed migratory gem-fluorolactonization of ene-carboxylic acids. Reaction of 4-methylenealkanoic acid derivatives with Selectfluor in the presence of Pd(OAc)2 (1.0 mol %) at room temperature affords fluorolactones in go ...
2024Chlorination of amides: Kinetics and mechanisms of formation of N-chloramides and their reactions with phenolic compounds
Amides are common constituents in natural organic matter and synthetic chemicals. In this study, we investi-gated kinetics and mechanisms of the reactions of chlorine with seven amides, including acetamide, N-meth-ylformamide, N-methylacetamide, benzamide, ...
2023A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks
Wendy Lee Queen, Jordi Espin Marti, Jocelyn Richard Roth, Till Marian Schertenleib, Nazanin Taheri, Ilia Kochetygov, Anita Justin, Sophia Alessandra Pache
The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...
WILEY-V C H VERLAG GMBH2023Simultaneous Generation of Methyl Esters and CO in Lignin Transformation
Paul Joseph Dyson, Mingyang Liu
Lignin is an abundant renewable carbon source. Due to its complex structure, utilization of lignin is very challenging. Herein, we describe an efficient strategy for the simultaneous utilization of lignin, in which the methoxy groups in lignin react with c ...
WILEY-V C H VERLAG GMBH2022