Concept
Néogène
Publications associées (5)
Why are sec-alkylperoxyl bimolecular self-reactions orders of magnitude faster than the analogous reactions of tert-alkylperoxyls? The unanticipated role of CH hydrogen bond donation
High-level ab initio calculations are used to identify the mechanism of secondary (and primary) alkylperoxyl radical termination and explain why their reactions are much faster than their tertiary counterparts. Contrary to existing literature, the decompos ...
Royal Soc Chemistry2016Shifting gear, quickly
Atmospheric methane (CH4) recorded in Antarctic ice cores represents the closest ice proxy available for Greenland temperature changes beyond times when Greenland climate records are available. The record over four climatic cycles from the Vostok ice core ...
American Geophysical Union (AGU)2009