Concept

Classification géochimique des éléments

Publications associées (40)

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

2023

GeSn as next-generation material for short-wave infrared single-photon detection

Andrea Giunto

In recent years, the automotive industry has aspired to bring self-driving vehicles to the generalpublic and light detection and ranging (LiDAR) sensors have emerged as the preferred solution forcar vision systems. At present, LiDAR technologies employ exp ...

EPFL2023

Revealing cation and metal gradients in and underneath passive films of the stainless steel 1.4652 in acidic and alkaline electrolytes with angular resolved dual energy X-ray photo-electron spectroscopy

Stefano Mischler, Patrik Schmutz, Anna Neus Igual Muñoz, Roland Hauert

Passive films on the superaustenitic stainless steel 1.4652 were studied using angular resolved hard X-ray photo-electron spectroscopy (HAXPES), which provides an increased information depth compared to conventional X-ray photo-electron spectroscopy (XPS). ...

Hoboken2023

Assessing the persistence of chalcogen bonds in solution with neural network potentials

Rubén Laplaza Solanas, Frédéric Célerse, Veronika Juraskova

Non-covalent bonding patterns are commonly harvested as a design principle in the field of catalysis, supramolecular chemistry, and functional materials to name a few. Yet, their computational description generally neglects finite temperature and environme ...

2022

Activation of small molecules promoted by multimetallic complexes supported by redox active ligands

Davide Toniolo

The activation of small molecule is a topic of high current interest. A variety of homogeneous end heterogeneous catalysts have been studied to be able to promote chemical transformation of industrial relevance under mild condition and therefore decrease t ...

EPFL2020

Lithium in red giant stars: Constraining non-standard mixing with large surveys in the Gaia era

Pierre North

Context. Li is extensively known to be a good tracer of non-standard mixing processes occurring in stellar interiors. Aims. We present the results of a new large Li survey in red giant stars and combine it with surveys from the literature to probe the impa ...

EDP SCIENCES S A2020

Element location and classification following a damage event of a near-full-scale deployable tensegrity structure

Ian Smith, Ann Christine Sychterz

Current infrastructure is designed and built such that it must resistall possible loads. This leads to overdesigned structures that are inefficient in terms energy and cost. A structure that can self-identify damage, adapt, and learn for future events resu ...

2019

Thermal activation and aging of a V2O3/WO3-TiO2 catalyst for the selective catalytic reduction of NO with NH3

Davide Ferri, Oliver Kröcher, Adrian Marberger, Rob Jeremiah G. Nuguid

Real-world vanadium-based catalysts for the selective catalytic reduction (SCR) of NO with NH3 are occasionally exposed to high temperatures, which can induce catalyst aging. In this work, a 2.0 wt% V2O5/WO3-TiO2 catalyst based on commercial WO3-TiO2 was l ...

ELSEVIER SCIENCE BV2019

Fe-Ni ideality during core formation on Earth

James Badro

Earth's core is essentially composed of a light-element bearing iron-nickel alloy (Birch 1964). The nickel content in the core has negligible effects on physical properties such as density and compressibility (e.g., Lin et al. 2003; Kantor et al. 2007; Mar ...

MINERALOGICAL SOC AMER2018

Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich

Rosario Scopelliti, Marinella Mazzanti, Rory Patrick Kelly

Organometallic multi-decker sandwich complexes containing f-elements remain rare, despite their attractive magnetic and electronic properties. The reduction of the Ce-III siloxide complex, [KCeL4] (1; L = OSi(OtBu)(3)), with excess potassium in a THF/tolue ...

2017

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