Concept

Oxygène solide

Publications associées (41)

Switchable wetting of oxygen-evolving oxide catalysts

The surface wettability of catalysts is typically controlled via surface treatments that promote catalytic performance. Here we report on potential-regulated hydrophobicity/hydrophilicity at cobalt-based oxide interfaces with an alkaline solution. The swit ...

NATURE PORTFOLIO2021

Ozone concentration measured during the Arctic Ocean 2018 expedition

Julia Schmale, Andrea Baccarini

Ozone was measured with a 2B Technology ozone monitor (model 205). The concentration is reported as a mixing ratio in parts per billion [ppb], at 60 seconds average. Ozone is a trace gas that can be formed directly in the troposphere (the most important fo ...

2020

Structural Screening and Design of Platinum Nanosamples for Oxygen Reduction

Kevin Rossi

Nanocatalyst-by-design promises to empower the next generation of electrodes for energy devices. However, current numerical methods consider individual and often geometrical closed-shell nanoparticles, neglecting how the coexistence of several and structur ...

AMER CHEMICAL SOC2020

Oxygen evolution reaction catalyzed by first-row transition metal oxides: stability and mechanism

Aliki Moysiadou

Water splitting offers the opportunity for storing solar energy and, thus, producing carbon-neutral and renewable solar fuels. The process, known as artificial photosynthesis, is limited by the electrocatalytic conversion of water into molecular oxygen. El ...

EPFL2020

Trellises of Molecular Oxygen on Anatase TiO2(101)

Klaus Kern, Christian Alexander Stephan Dette, Feliciano Giustino, Shai Mangel

The adsorption of molecular oxygen has important implications for the catalytic activity of oxide surfaces, especially for oxidative TiO2 catalysts. In the case of anatase TiO2(101), several studies have noted the importance of surface defects which stabil ...

2019

Stability of metallo-porphyrin networks under oxygen reduction and evolution conditions in alkaline media

Klaus Kern, Jan Gui-Hyon Dreiser, Markus Etzkorn, Claudius Morchutt, Sebastian Stepanow, Benjamin Wurster

Transition metal atoms stabilised by organic ligands or as oxides exhibit promising catalytic activity for the electrocatalytic reduction and evolution of oxygen. Built-up from earth-abundant elements, they offer affordable alternatives to precious-metal b ...

2019

A systematic investigation on the bactericidal transient species generated by photo-sensitization of natural organic matter (NOM) during solar and photo Fenton disinfection of surface waters

César Pulgarin, Stefanos Giannakis, Mona Kohantorabi, Ling Feng

In this work, the role of dissolved oxygen in the solar and the photo-Fenton-mediated E. coli inactivation process was put under scrutiny. The effect of transient species that were produced in the presence of various natural organic matter isolates (NOM), ...

ELSEVIER SCIENCE BV2019

Oxidative cleavage of -O-4 bonds in lignin model compounds with a single-atom Co catalyst

Paul Joseph Dyson, Xile Hu, Zhaofu Fei, Antoine Philippe Van Muyden, Xiang Li, Lichen Bai, Zhangjun Huang, Xinjiang Cui, Sijie Liu

Single-atom catalysts are emerging as primary catalysts for many reactions due to their 100% utilization of active metal centers leading to high catalytic efficiencies. Herein, we report the use of a single-atom Co catalyst for the oxidative cleavage of th ...

2019

Formation of N-Nitrosodimethylamine during Chloramination of Secondary and Tertiary Amines: Role of Molecular Oxygen and Radical Intermediates

Urs von Gunten, Stephanie Spahr

N-Nitrosodimethylamine (NDMA) is a carcinogenic disinfection byproduct from water chloramination. Despite the identification of numerous NDMA precursors, essential parts of the reaction mechanism such as the incorporation of molecular O-2 are poorly unders ...

American Chemical Society2017

Strong Interplay between the Electron Spin Lifetime in Chemically Synthesized Graphene Multilayers and Surface-Bound Oxygen

László Forró, Bálint Náfrádi

The electron spin lifetime in an assembly of chemically synthesized graphene sheets was found to be extremely sensitive to oxygen. Introducing small concentrations of physisorbed O-2 onto the graphene surface reduced the exceptionally long 140 ns electron ...

Wiley-V C H Verlag Gmbh2015

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