Publications associées à Stœchiométrie

Strategic advantages of reactive polyiodide melts for scalable perovskite photovoltaics

Despite tremendous progress in efficiency and stability, perovskite solar cells are still facing the challenge of upscaling. Here we present unique advantages of reactive polyiodide melts for solvent- and adduct-free reactionary fabrication of perovskite f ...

NATURE PUBLISHING GROUP2019

Atomic Layer Deposition on Dispersed Materials in Liquid Phase by Stoichiometrically Limited Injections

Jeremy Luterbacher, Benjamin Pierre Le Monnier, Farzaneh Talebkeikhah, Frederick Georges Wells

Atomic layer deposition (ALD) is a well‐established vapor‐phase technique for depositing thin films with high conformality and atomically precise control over thickness. Its industrial development has been largely confined to wafers and low‐surface‐area ma ...

2019

Highly Selective Oxidation and Depolymerization of α,γ-Diol Protected Lignin

Jeremy Luterbacher, Jean Thierry C Behaghel de Bueren, Wu Lan

Lignin oxidation offers a potential sustainable pathway to oxygenated aromatic molecules. However, current methods that use real lignin tend to have low selectivity and a yield that is limited by lignin degradation during its extraction. We developed stoic ...

2019

Methane oxidation over a honeycomb Pd-only three-way catalyst under static and periodic operation

Davide Ferri, Oliver Kröcher

Natural gas is receiving increasing awareness as fuel for passenger vehicles due to its very low specific CO2 emissions. However, control of CH4 emissions from natural gas combustion in stoichiometric engines requires a specific three-way catalyst (TWC). T ...

Elsevier Science Bv2018

Insertion of germanium atoms in high- nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [ Rh13Ge( CO) 25] 3-, [ Rh14Ge2( CO) 30] 2-and [ Rh12Ge( CO) 27] 4-clusters+

Paul Joseph Dyson, Silvia Ruggieri

The reaction of the Rh-7(CO)(16) cluster anion with Ge2+ salts, in different stoichiometric ratios and under different atmospheres, leads to the formation of new heterometallic Rh-Ge clusters, representing the first known examples of Rh carbonyl comp ...

ROYAL SOC CHEMISTRY2018

On decoupling rate processes in chemical reaction systems - Methods and applications

Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Diogo Filipe Mateus Rodrigues

Models of chemical reaction systems can be complex as they need to include information regarding the reactions and the mass and heat transfers. The commonly used state variables, namely, concentrations and temperatures, express the interplay between many p ...

2018

Quantum-state-controlled channel branching in cold Ne(3P2)+Ar chemi-ionization

Andreas Osterwalder, Sean Dennis Steven Gordon, Junwen Zou, Silvia Tanteri

A prerequisite to gain a complete understanding of the most basic aspects of chemical reactions is the ability to perform experiments with complete control over the reactant degrees of freedom. By controlling these, details of a reaction mechanism can be i ...

2018

Extent Computation under Rank-deficient Conditions

Dominique Bonvin, Julien Léo Billeter

The identification of kinetic models can be simplified via the computation of extents of reaction on the basis of invariants such as stoichiometric balances. With extents, one can identify the structure and the parameters of reaction rates individually, wh ...

2017

Concept and Applications of Extents in Chemical Reaction Systems

Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Sriniketh Srinivasan, Diogo Filipe Mateus Rodrigues

Models of chemical reaction systems can be quite complex as they typically include information regarding the reactions, the various transfers of heat and mass, as well as the effects of the inlet and outlet flows. It is well known that a linear transformat ...

2017

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Stœchiométrie

Strategic advantages of reactive polyiodide melts for scalable perovskite photovoltaics

Atomic Layer Deposition on Dispersed Materials in Liquid Phase by Stoichiometrically Limited Injections

Highly Selective Oxidation and Depolymerization of α,γ-Diol Protected Lignin

Methane oxidation over a honeycomb Pd-only three-way catalyst under static and periodic operation

Insertion of germanium atoms in high- nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [ Rh13Ge( CO) 25] 3-, [ Rh14Ge2( CO) 30] 2-and [ Rh12Ge( CO) 27] 4-clusters+

On decoupling rate processes in chemical reaction systems - Methods and applications

Quantum-state-controlled channel branching in cold Ne(3P2)+Ar chemi-ionization

GEOTEXTILE

Extent Computation under Rank-deficient Conditions

Concept and Applications of Extents in Chemical Reaction Systems

Graph Chatbot

Chattez avec Graph Search

Insertion of germanium atoms in high- nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [ Rh13Ge( CO) 25] 3-, [ Rh14Ge2( CO) 30] 2-and [ Rh12Ge( CO) 27] 4-clusters+

On decoupling rate processes in chemical reaction systems - Methods and applications

Atomic Layer Deposition on Dispersed Materials in Liquid Phase by Stoichiometrically Limited Injections

Highly Selective Oxidation and Depolymerization of α,γ-Diol Protected Lignin

Methane oxidation over a honeycomb Pd-only three-way catalyst under static and periodic operation

Quantum-state-controlled channel branching in cold Ne(3P2)+Ar chemi-ionization

GEOTEXTILE

Extent Computation under Rank-deficient Conditions

Concept and Applications of Extents in Chemical Reaction Systems

Strategic advantages of reactive polyiodide melts for scalable perovskite photovoltaics