Concept

Aniline

Publications associées (57)

The effect of UV-irradiation (under short-circuit condition) on dye-sensitized solar cells sensitized with a Ru-complex dye functionalized with a (diphenylamino)styryl-thiophen group

Ulf Anders Hagfeldt, Kazuteru Nonomura, Rong Zhang

A new Ru complex, cis-di(thiocyanato)(2,2'-bipyridine-4,4'-dicarboxylic acid)(4,4'-bis(2-(5-(2-(4-diphenylaminophenyl) ethenyl)-thiophen-2-yl)ethenyl)-2,2'-bipyridine)ruthenium(II) (named E322) was synthesized for use in dye-sensitized solar cells (DSCs). ...

2009

Self-assembly of boron-based supramolecular structures

Nicolas Christinat

This work describes the synthesis and characterization of boronic acid-based supramolecular structures. Macrocycles, dendritic structures, polymers, rotaxanes, and cages were assembled using four types of reversible reactions. The key point of the strategy ...

EPFL2008

Photoinduced absorption spectroscopy as a tool in the study of dye-sensitized solar cells

Ulf Anders Hagfeldt

Photoinduced absorption spectroscopy, where the excitation is provided by a square-wave modulated (on/off) monochromatic light source, is a versatile tool in the study of dye-sensitized solar cells. Spectra of transient species, such as the oxidized dye, c ...

2008

Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids: II. Rhodium-catalyzed hydrogenation of arenes

Paul Joseph Dyson, Chenxu Zhao, Ning Yan

Rhodium nanoparticles stabilized by the ionic-liq.-like copolymer N-Vinyl-2-pyrrolidone-1-vinyl-3-butylimidazolium chloride-1-vinyl-3-ethylimidazolium bromide copolymer were used to catalyze the hydrogenation of benzene and other arenes in ILs. The nanopar ...

2007

Excited-State Dynamics of Donor−Acceptor Bridged Systems Containing a Boron−Dipyrromethene Chromophore: Interplay between Charge Separation and Reorientational Motion

Natalie Renuka Banerji, Eric Vauthey

The excited-state dynamics of a series of electron donor−acceptor bridged systems (DABS) consisting of a boron−dipyrromethene chromophore covalently linked to a dinitro-substituted triptycene has been investigated using femtosecond time-resolved spectrosco ...

2007

Electrochemically modified single-walled carbon nanotubes

Klaus Kern, Marko Burghard, Kannan Balasubramanian, Ralf Thomas Weitz, Eduardo Jian Hua Lee, Tilman Assmus

We report on the properties of electrochemically modified SWCNTs bearing a functional organic layer and a low density of noble metal nanoparticles, respectively. First, a novel approach to nanoscale pH sensors is demonstrated which involves the gentle modi ...

2007

Palladium-Catalyzed, Modular Synthesis of Highly Functionalized Indoles and Tryptophans by Direct Annulation of Substituted o-Haloanilines and Aldehydes

Jieping Zhu

One-pot synthesis of indoles by a palladium-catalyzed annulation of o-haloanilines and aldehydes has been developed. Coupling of o-iodoaniline with aldehyde is realized under mild ligandless conditions [Pd(OAc)2, DABCO, DMF, 85 DegC], whereas X-Phos is fou ...

2006

In search of simplicity and flexibility: a rational access to twelve fluoroindolecarboxylic acids

Assunta Ginanneschi

All twelve indolecarboxylic acids carrying both a fluorine substituent and a carboxy group at the benzo ring have been prepd. either directly from the corresponding fluoroindoles or from the chlorinated derivs. by hydrogen/metal permutation ("metalation"), ...

2006

Photoelectron Spectroscopy of Doped Helium Droplets

Marcel Drabbels, Evgeniy Loginov, Dominic Rossi

The photoionization dynamics of aniline doped helium droplets has been investigated by photoelectron spectroscopy. The photoelectron spectra resemble closely that of gas phase aniline, except for a dropletsize- dependent shift. This shift is caused by lowe ...

2005

Electrochemical modification and photoelectronic properties of carbon nanotubes

Kannan Balasubramanian

This thesis reports on the investigations performed on electrochemical functionalization and photoelectronic transport properties of individual single-wall carbon nanotubes (SWCNTs). The first part of the thesis is concerned with the controlled modificatio ...

EPFL2005

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