Publications associées à Thorium

Carboxylic acid isomer-directed synthesis of CdS nanocluster isomers

Selective synthesis of nanocluster (NC) isomers with tailored structures holds significant importance for enhancing their applications. Here, we develop an effective strategy for the selective synthesis of CdS NC isomers through the judicious choice of a p ...

Royal Soc Chemistry2024

Secondary Phase CeO2 Precipitates in Ce,Er-Doped Na0.5La0.5MoO4 Single Crystals Grown by Czochralski Method

Philippe Buffat, Elena Suvorova Buffat

Analytical scanning and transmission electron microscopy were used to study the microstructure of Ce,Er-doped Na0.5La0.5MoO4 laser crystals. Crystals were grown by the Czochralski method from the melts with a nominal composition of Na0.5La0.5−xCexEr0.005Mo ...

2023

Theory-guided development of homogeneous catalysts for the reduction of CO2 to formate, formaldehyde, and methanol derivatives

Matthew Wodrich, Shubhajit Das, Anne-Clémence Corminboeuf, Hanna Hinrika Cramer

The stepwise catalytic reduction of carbon dioxide (CO2) to formic acid, formaldehyde, and methanol opens non-fossil pathways to important platform chemicals. The present article aims at identifying molecular control parameters to steer the selectivity to ...

2023

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Rosario Scopelliti, Marinella Mazzanti, Fang-Che Hsueh, Luciano Barluzzi

Thorium nitrides are likely intermediates in the reported cleavage and functionalization of dinitrogen by molecular thorium complexes and are attractive compounds for the study of multiple bond formation in f-element chemistry, but only one example of thor ...

2022

Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Andrzej Sienkiewicz, Zhaowen Dong

Mesoionic imidazolylidenes are recognized as excellent electron-donating ligands in organometallic and main group chemistry. However, these carbene ligands typically show poor π-accepting properties. We have performed a computational analysis of 71 mesoion ...

2021

Precipitation Pathways: In Situ Liquid SAXS Studies on the Early Stage of Calcium Carbonate Formation (Part. Part. Syst. Charact. 6/2019)

Andrea Testino, Agnese Carino, Mohammad Reza Andalibi

In article number 1800482, Andrea Testino and co‐workers investigate calcium carbonate clusters in‐situ by small angle X‐ray scattering using a liquid jet setup at constant pH, temperature, and saturation level. The saturation is kept constant and below th ...

2020

Corrosion behaviour of nitrided ferritic stainless steels for use in solid oxide fuel cell devices

Jan Van Herle, Manuel Bianco, Stéphane François Jean Poitel

Plasma nitriding was applied to ferritic stainless steel substrates to improve their performances as interconnects for solid oxide fuel cell devices. The samples underwent electrical conductivity test and SEM/EDS, TEM/EDS, environmental-SEM analyses. The f ...

2020

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Alberto Fabrizio, Luciano Barluzzi

Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U & xe001;N & xe001;U bonding imposed by the supporting ligand. The U4+-U4+ nitride complexes, [NBu4][{(((BuO)-Bu-t)(3)SiO)(3)U}(2)(mu-N)], [NB ...

2019

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Thorium

Carboxylic acid isomer-directed synthesis of CdS nanocluster isomers

Secondary Phase CeO2 Precipitates in Ce,Er-Doped Na0.5La0.5MoO4 Single Crystals Grown by Czochralski Method

Theory-guided development of homogeneous catalysts for the reduction of CO2 to formate, formaldehyde, and methanol derivatives

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study

Circularly Polarized Transmitarray Antenna for CubeSat Intersatellite Links in K-Band

Precipitation Pathways: In Situ Liquid SAXS Studies on the Early Stage of Calcium Carbonate Formation (Part. Part. Syst. Charact. 6/2019)

Corrosion behaviour of nitrided ferritic stainless steels for use in solid oxide fuel cell devices

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

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Chattez avec Graph Search

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Precipitation Pathways: In Situ Liquid SAXS Studies on the Early Stage of Calcium Carbonate Formation (Part. Part. Syst. Charact. 6/2019)

Circularly Polarized Transmitarray Antenna for CubeSat Intersatellite Links in K-Band

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Secondary Phase CeO2 Precipitates in Ce,Er-Doped Na0.5La0.5MoO4 Single Crystals Grown by Czochralski Method

Corrosion behaviour of nitrided ferritic stainless steels for use in solid oxide fuel cell devices

Theory-guided development of homogeneous catalysts for the reduction of CO2 to formate, formaldehyde, and methanol derivatives

Carboxylic acid isomer-directed synthesis of CdS nanocluster isomers

Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study