Concept

Teinture naturelle

Publications associées (117)

Synthesis, characterization and ab initio investigation of a panchromatic ullazine–porphyrin photosensitizer for dye-sensitized solar cells

Mohammad Khaja Nazeeruddin, Ursula Röthlisberger, Basile Curchod, Magdalena Anna Marszalek, Negar Ashari Astani, Julien Edouard Frey, Simon Mathew

An ullazine unit was employed as a donor moiety in a donor-pi-acceptor (D-p-A) motif, employing the porphyrin macrocycle as a pi-system. Synthesis of this ullazine-porphyrin dyad containing sensitizer (SM63) was achieved and an investigation of the electro ...

2016

Porphyrin based sensitizer for dye-sensitized solar cell

Michael Graetzel, Shaik Mohammed Zakeeruddin, Fabrizio Giordano, Chenyi Yi

The present invention relates to compounds of formula (I) based on a porphyrin core and a π-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and ne ...

2016

Thieno[3,4-b]pyrazine as an Electron Deficient pi-Bridge in D-A-pi-A DSCs

Michael Graetzel, Aswani Yella

Thieno[3,4-b]pyrazine (TPz) is examined as an electron deficient pi-bridge enabling near-infrared (NIR) spectral access in dye sensitized solar cells (DSCs). Seven dissymmetric dyes for DSCs were synthesized (NL2-NL8) with TPz as the pi-bridge utilizing pa ...

Amer Chemical Soc2016

Factors Affecting the Performance of Champion Silyl-Anchor Carbazole Dye Revealed in the Femtosecond to Second Studies of Complete ADEKA-1 Sensitized Solar Cells

Ulf Anders Hagfeldt, Enrico Polanski, Jan Ernest Sobus

Record laboratory efficiencies of dye-sensitized solar cells have been recently reported using an alkoxysilyl-anchor dye, ADEKA-1 (over 14%). In this work we use time-resolved techniques to study the impact of key preparation factors (dye synthesis route, ...

Wiley-Blackwell2016

Accurate and Inexpensive Prediction of the Color Optical Properties of Anthocyanins in Solution

Iurii Timrov

The simulation of the color optical properties of molecular dyes in liquid solution requires the calculation of time evolution of the solute absorption spectra fluctuating in the solvent at finite temperature. Time-averaged spectra can be directly evaluate ...

Amer Chemical Soc2015

Selective detection of Al3+ and citric acid with a fluorescent amphiphile

Kay Severin

An amphiphilic fluorescent dye with a disulfonated BODIPY head group and a heptadecyl side chain is described. In buffered aqueous solution, the amphiphile can form aggregates with a critical micelle concentration of similar to 20 mu M. The aggregation of ...

Royal Society of Chemistry2015

Laser desorption/ionization mass spectrometry of dye-sensitized solar cells: identification of the dye-electrolyte interaction

Ulf Anders Hagfeldt

Dye-sensitized solar cells (DSCs) have great potential to provide sustainable electricity from sunlight. The photoanode in DSCs consists of a dye-sensitized metal oxide film deposited on a conductive substrate. This configuration makes the photoanode a per ...

Wiley-Blackwell2015

Array-based sensing of purine derivatives with fluorescent dyes

Kay Severin, Ziya Köstereli

Natural and synthetic purine derivatives such as caffeine, theophylline, 6-mercaptopurine and 8-chlorotheophylline are important drugs. Due to the structural similarity of these compounds, it is intrinsically difficult to prepare chemosensors for their sel ...

Royal Soc Chemistry2015

Dye adsorption on TiO2 electrodes studied using modulated photocurrent measurements

Ulf Anders Hagfeldt

An in-situ modulated photocurrent technique to study kinetics of dye adsorption and to determine binding constants of dye molecules on the TiO 2 surface is presented. An AC-photocurrent signal is measured, when a TiO2 electrode is in contact with the dye b ...

2014

Design of Ru(II) sensitizers endowed by three anchoring units for adsorption mode and light harvesting optimization

Mohammad Khaja Nazeeruddin, Filippo de Angelis

We report the design, synthesis and computational investigation of a class of Ru(II)-dyes based on mixed bipyridine ligands for use in dye-sensitized solar cells. These dyes are designed to preserve the optimal anchoring mode of the prototypical N719 sensi ...

Elsevier2014

Graph Chatbot

Chattez avec Graph Search

Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.

AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.

Connectez-vous pour utiliser Chat avec Graph Search