Orbital magnetization

In quantum mechanics, orbital magnetization, Morb, refers to the magnetization induced by orbital motion of charged particles, usually electrons in solids. The term "orbital" distinguishes it from the contribution of spin degrees of freedom, Mspin, to the total magnetization. A nonzero orbital magnetization requires broken time-reversal symmetry, which can occur spontaneously in ferromagnetic and ferrimagnetic materials, or can be induced in a non-magnetic material by an applied magnetic field. The orbital magnetic moment of a finite system, such as a molecule, is given classically by where J(r) is the current density at point r. (Here SI units are used; in Gaussian units, the prefactor would be 1/2c instead, where c is the speed of light.) In a quantum-mechanical context, this can also be written as where −e and me are the charge and mass of the electron, Ψ is the ground-state wave function, and L is the angular momentum operator. The total magnetic moment is where the spin contribution is intrinsically quantum-mechanical and is given by where gs is the electron spin g-factor, μB is the Bohr magneton, ħ is the reduced Planck constant, and S is the electron spin operator. The orbital magnetization M is defined as the orbital moment density; i.e., orbital moment per unit volume. For a crystal of volume V composed of isolated entities (e.g., molecules) labelled by an index j having magnetic moments morb, j, this is However, real crystals are made up out of atomic or molecular constituents whose charge clouds overlap, so that the above formula cannot be taken as a fundamental definition of orbital magnetization. Only recently have theoretical developments led to a proper theory of orbital magnetization in crystals, as explained below. For a magnetic crystal, it is tempting to try to define where the limit is taken as the volume V of the system becomes large. However, because of the factor of r in the integrand, the integral has contributions from surface currents that cannot be neglected, and as a result the above equation does not lead to a bulk definition of orbital magnetization.