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Helical frontier molecular orbitals (MOs) appear in disubstituted allenes and even-n cumulenes. Chiral molecules are optically active, but while these molecules are single-handed chiral, p-orbitals of both helicities are present. Here we computationally ex ...
Twisted bilayer graphene (TBG) is a two-dimensional chiral material whose optical activity is remarkably strong for its atomic thickness. While the chiral optical properties of TBG are currently well understood, the optical activity of quantum dots (QDs) m ...
We provide a detailed discussion on the electromagnetic modeling and classification of polarization converting bianisotropic metasurfaces. To do so, we first present a general approach to compute the scattering response of suchmetasurfaces, which relies on ...
The absence of centrosymmetry in chiral and polar crystal structures is the reason for many technical relevant physical properties like optical birefringence or ferroelectricity. Other chirality related properties that are actually intensively investigated ...
Wave manipulation at a subwavelength scale has recently attracted significant interest, especially for low-frequency wave propagation, from acoustic to microwave devices. Recently, a few methods achieving subwavelength routing using locally resonant metama ...
Chirality is present as a trend of research in biological and chemical communities for it has a significant effect on physiological properties and pharmacological effects. Further, manipulating specific morphological chirality recently has emerged as a pro ...
The chiral magnetic effect (CME) is a quantum relativistic effect that describes the appearance of an additional electric current along a magnetic field. It is caused by an asymmetry between the number densities of left- and right-handed fermions, which ca ...
We address the intrinsic polarization and screening of an external electric field in a broad range of ordered and twisted configurations of multilayer graphene, using an ab initio approach combining density functional theory and the Wannier function formal ...
We report herein the first examples of a palladiumcatalyzed enantioselective Cacchi reaction for the synthesis of indoles bearing a chiral C2-aryl axis. In the presence of a catalytic amount of Pd(OAc)2 and (R,R)-QuinoxP* ligand, reaction of N-aryl(alkyl)s ...
It has recently been proposed that combining chirality with topological band theory results in a totally new class of fermions. Understanding how these unconventional quasiparticles propagate and interact remains largely unexplored so far. Here, we use sca ...
