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Photocatalytic approaches for the production of solar hydrogen or hydrocarbons are interesting as they provide a sustainable alternative to fossil fuels. Research has been focused on water splitting and on the synthesis of photocatalyst materials and compo ...
Even though advanced power generation systems offer higher efficiencies than simpler gas turbines, severe area and weight restrictions keep on impeding their widespread implementation in offshore petroleum industry. If those restrictions could be resolved, ...
Spherical assemblies of the type [PdnL2n]2n+ can be obtained from PdII salts and curved N-donor ligands, L. It is well established that the bent angle, α, of the ligand is a decisive factor in the self-assembly process, with larger angles leading to comple ...
This study evaluates two different scenarios of an integrated system to generate electricity for a charging station using proton exchange membrane fuel cell (PEMFC) and solid oxide fuel cell (SOFC). To improve the efficiency, the exhaust heat of these two ...
Supercritical water gasification (SCWG) is a promising and versatile technology for the conversion of a variety of wet biomass streams into renewable natural gas. In this work, the focus was set on methane production with the help of an active and stable m ...
Direct methanation of biogas converts the CO2 in raw-biogas to methane, enabling higher methane yield and an elelctricity storage option via Power-to-Gas. As the thermodynamic equilibrium limits the methane yield, unreacted hydrogen has to be removed and r ...
With the future decarbonization of the electricity production, gas turbines will be an important tool for the stabilization of the electricity grid by meeting the peak of energy demand using zero-carbon fuels like synthetic gas and hydrogen.The combustion ...
The present case study is multi-criteria performance analysis of EPFL’s heat pump for different working fluids. The heat pump is based on a 2-stage vapour compression cycle which is modelled using the software Belsim VALI for 7 low-GWP refrigerants. The si ...
We study many-body localization (MBL) in a pair-hopping model exhibiting strong fragmentation of the Hilbert space. We show that several Krylov subspaces have both ergodic statistics in the thermodynamic limit and a dimension that scales much slower than t ...
Molecular simulations allow to investigate the behaviour of materials at the atomistic level, shedding light on phenomena that cannot be directly observed in experiments. Accurate results can be obtained with ab initio methods, while simulations of large-s ...