Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols (methanol, ethanol, propanol, and butanol)
are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines. The general chemical formula for alcohol fuel is CnH2n+1OH.
Most methanol is produced from natural gas, although it can be produced from biomass using very similar chemical processes. Ethanol is commonly produced from biological material through fermentation processes. Biobutanol has the advantage in combustion engines in that its energy density is closer to gasoline than the simpler alcohols (while still retaining over 25% higher octane rating); however, biobutanol is currently more difficult to produce than ethanol or methanol. When obtained from biological materials and/or biological processes, they are known as bioalcohols (e.g. "bioethanol"). There is no chemical difference between biologically produced and chemically produced alcohols.
One advantage shared by the four major alcohol fuels is their high octane rating. This tends to increase their fuel efficiency and largely offsets the lower energy density of vehicular alcohol fuels (as compared to petrol/gasoline and diesel fuels), thus resulting in comparable "fuel economy" in terms of distance per volume metrics, such as kilometers per liter, or miles per gallon.
Methanol fuel and Ethanol fuel
Methanol and ethanol can both be derived from fossil fuels, biomass, or from carbon dioxide and water. Ethanol has most commonly been produced through fermentation of sugars, and methanol has most commonly been produced from synthesis gas, but there are more modern ways to obtain these fuels. Enzymes can be used instead of fermentation. Methanol is the simpler molecule, and ethanol can be made from methanol. Methanol can be produced industrially from nearly any biomass, including animal waste, or from carbon dioxide and water or steam by first converting the biomass to synthesis gas in a gasifier.
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Ethanol, an alcohol fuel, is an important fuel for the operation of internal combustion engines that are used in cars, trucks, and other kinds of machinery. Ethanol was first isolated from wine in approximately 1100 and was found to burn shortly thereafter. These early solutions distilled from wine-salt mixtures were referred to as aqua ardens (burning water) or aqua flamens (flaming water) and had such low alcohol content that they burned without producing noticeable heat.
Le butanol peut être utilisé comme carburant dans un moteur à combustion interne. Il ressemble plus à essence qu'à éthanol. Un hydrocarbure en C4, le butanol est un carburant de remplacement et fonctionne donc dans les véhicules conçus pour être utilisés avec de l'essence sans modification . Il peut être produit à partir de biomasse (comme "biobutanol") ainsi que de combustible fossile s (comme "pétrobutanol" ). Le biobutanol et le pétrobutanol ont les mêmes propriétés chimiques. Le butanol issu de la biomasse est appelé biobutanol.
vignette|Pompe proposant du carburant E85. Le carburant E85, également appelé superéthanol, est un mélange constitué d'un biocarburant (ou agrocarburant), l'éthanol, et d'essence SP95. C'est un vecteur énergétique majoritairement renouvelable qui permet de limiter la consommation en énergie fossile, mais qui entre en concurrence avec les surfaces agricoles dédiées à l'alimentation humaine. Il permet de remplir les réservoirs des véhicules polycarburant (qui fonctionnent indifféremment à l’essence (SP95, E10, SP98) et au superéthanol).
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