Concept

Polymorphisme (chimie)

Publications associées (182)

Wrinkling crystallography on spherical surfaces

Pedro Miguel Nunes Pereira de Almeida Reis

We present the results of an experimental investigation on the crystallography of the dimpled patterns obtained through wrinkling of a curved elastic system. Our macroscopic samples comprise a thin hemispherical shell bound to an equally curved compliant s ...

2014

Enhanced crystallinity in organic-inorganic lead halide perovskites on mesoporous TiO2 via disorder-order phase transition

Ulf Anders Hagfeldt

Organic-inorganic halide perovskite (OIHP) compounds are very interesting materials for device application in, for example, solar cells, electro-optics, and electronic circuits. In this report, we investigated OIHPs reported as CH3NH3PbI3-xClx (MAPbI 3-xCl ...

2014

Nanocrystalline Rutile Electron Extraction Layer Enables Low-Temperature Solution Processed Perovskite Photovoltaics with 13.7% Efficiency

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Aswani Yella, Leo-Philipp Heiniger

We demonstrate low-temperature (70 degrees C) solution processing of TiO2/CH3NH3PbI3 based solar cells, resulting in impressive power conversion efficiency (PCE) of 13.7%. Along with the high efficiency, a strikingly high open circuit potential (V-OC) of 1 ...

American Chemical Society2014

Synthesis and Phase Stability of Metastable Bixbyite V2O3 Colloidal Nanocrystals

Raffaella Buonsanti

We have recently developed a colloidal route to vanadium sesquioxide (V2O3) nanocrystals with a metastable bixbyite crystal structure. In addn. to being one of the first reported observations of the bixbyite phase in V2O3, it is also one of the first succe ...

2013

Cimetidine, C10H16N6S, form C: crystal structure and modelling of polytypes using the superspace approach

Gervais Chapuis, Alla Arakcheeva, Philip Pattison

An efficient method for modelling a polytypic family is presented with the example of cimetidine in the form C polymorph. The method exploits the (3 + 1)-dimensional superspace model, which is a powerful tool for the description, prediction and understandi ...

Wiley-Blackwell2013

Formation of cubic structured (Al1-xCrx)(2+delta)O-3 and its dynamic transition to corundum phase during cathodic arc evaporation

Alireza Karimi, Hossein Najafi

Mixed aluminum-chromium oxide coatings in the form of (Al,Cr)(2)O-3 solid solutions have attracted extensive research interest during the past years due to their successful use for challenging wear applications and the comparative ease of their moderate-te ...

Elsevier Science Sa2013

Powder crystallography of pharmaceutical materials by combined crystal structure prediction and solid-state H-1 NMR spectroscopy

David Lyndon Emsley

A protocol for the ab initio crystal structure determination of powdered solids at natural isotopic abundance by combining solid-state NMR spectroscopy, crystal structure prediction, and DFT chemical shift calculations was evaluated to determine the crysta ...

ROYAL SOC CHEMISTRY2013

Synthesis, characterization and X-ray crystal structures of two polymorphs of a cobalt(III) complex with a N3O2 pentadentate Schiff base ligand, and benzylamine: spectral and electrochemical studies

Kurt Schenk

The title complex [Co-III{(naph)(2)dpt}(bzlan)]BPh4, where (naph)(2)dpt stands for bis-(2-hydroxy-1-naphthaldimine)-N-dipropylenetriamine dianion and bzlan for benzylamine, has been synthesized and characterized by elemental analyses, IR, UV-Vis and H-1 NM ...

Springer2013

Plasticity in bcc single crystals investigated by Laue diffraction during micro-compression

Cécile Renée Maria Marichal

Body-centered cubic metals are of high technological interest: for example tungsten as potential plasma facing component in future fusion reactors, molybdenum employed in aircraft parts, niobium as superconducting magnets, etc. The characteristics of their ...

EPFL2013

Shock-induced deformation of Shergottites: Shock-pressures and perturbations of magmatic ages on Mars

Philippe Gillet, Pierre Beck

Shergottites and Chassignites practiced major deformation effects whose nature, magnitude and relevance were controversially evaluated and disputatively debated. Our studies of many shocked shergottites present, contrary to numerous previous reports, ample ...

Pergamon-Elsevier Science Ltd2013

Graph Chatbot

Chattez avec Graph Search

Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.

AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.

Connectez-vous pour utiliser Chat avec Graph Search