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Several important network applications cannot easily scale to higher data rates without requiring focusing just on the large traffic flows. Recent works have discussed algorithmic solutions that trade-off accuracy to gain efficiency for filtering and track ...
Gold and rhodium nanoparticles stabilized by a cationic polymer can be readily modified by anion exchange to afford nanoparticles that may be dispersed in a wide range of organic solvents and ionic liquids. The catalytic activity of the Rh nanoparticle dis ...
Due to high scaling order of MP2 and CCSD(T) methods, it is either difficult or at times even impossible to treat even moderately sized molecular systems with elaborate basis sets such as aug-cc-pVXZ (X = D, T, Q). In the present work, several structures o ...
This report describes a full study of the gold-catalyzed direct alkynylation of indoles, pyrroles, and thiophenes using alkynyl hypervalent iodine reagents, especially the study of the structural requirements of alkynyl benziodoxolones for an efficient ace ...
We present and validate BlastR, a method for efficiently and accurately searching non-coding RNAs. Our approach relies on the comparison of di-nucleotides using BlosumR, a new log-odd substitution matrix. In order to use BlosumR for comparison, we recoded ...
Two dinuclear oxo-bridged organogold(III) compounds, namely [(N,N,C)(2)Au-2(mu-O)]PF6 (with N,N,CH = 6-(1-methylbenzyl)-2,2'-bipyridine, Au(2)O1; or 6-(1,1-dimethylbenzyl)-2,2'-bipyridine, Au(2)O2), were previously prepared and characterised. Their so ...
Ce mémoire, réalisé sous mandat de la bibliothèque de l’Ecole Polytechnique Fédérale de Lausanne (EPFL), fait état de la publication en Open Access aujourd’hui. Il couvre ainsi les disciplines scientifiques présentes dans l’institution, plus particulièreme ...
Gold metallodrugs form a class of promising antiproliferative agents showing a high propensity to react with proteins. We exploit here X-ray absorption spectroscopy (XAS) methods [both X-ray absorption near-edge spectroscopy (XANES) and extended X-ray abso ...
To date, the use of gold for the synthesis of nanowires has proven to be nearly impossible to circumvent, regardless of the potential negative effects on the nanowires physical properties. In this paper, the synthesis of gallium arsenide nanowires without ...
Institute of Electrical and Electronics Engineers2011
Nowadays, gold compounds occupy a relevant position constituting a promising class of experimental anticancer metallodrugs. Several research efforts have been devoted to the investigations of the pharmacological properties of gold(I) complexes bearing phos ...